Emrick Research Group

Emrick Research Group - Publications (274 Peer-Reviewed; H-Index = 54)

Most Cited Papers (Top 10)


298.  Brown, M. U.; Seong, H.; Russell, T.P.; Emrick, T.  Zwitterionic Sulfonium Solfonate Polymers: Impacts of Substituents and Inverted Dipole.  Macromolecules  2023 56, 1105-1110.  DOI:10.1021/acs.macromol.2c02359

297.  Sonu, K. P.; Zhou, L.; Biswas, S.; Klier, J.; Balazs, A.C.; Emrick, T.; Peyton, S.R.  Strain-stiffening Hydrogels with Dynamic, Secondary Cross-Linking.  Langmuir 2023, 39, 2659-2666. DOI: 10.1021/acs.languir.2c03117.

296.  Barber, D.M.; Emrick, T.; Grason, G.M.; Crosby, A.J.  Self-Spinning Filaments for Autonomously Linked Microfibers.  Nature Chemistry 2023, article in press. doi.org/10.1038/s41467-023-36355-w.

295.  Zhou, L.; Yang, Z.; Pagaduan, J.N.; Emrick, T.  Fluorinated Zwitterionic Polymers as Dynamic Surface Coatings.  Polym. Chem. 2023, 14, 32-28.  DOI:10,1039/d2py01197b.

294.  Hamilton, H.; Meissner, C.; Emrick, T.; Bradley, L.C.  One-Step Synthesis of Biphasic, Cavity-Forming Polymer Particles via Dispersion Copolymerization of Styrene and Sulfobetaine Methacrylate  Macromol. Rapid Commun. 2023, 2200873  DOI 10.1012/marc.202200873.


293.  Yang, Z.; Snyder, D.; Pagaduan, J.N.; Waldman, A.; Crosby, A.J.; Emrick, T.  Mesoscale Polymer Surfactants: Photolithographic Production and Localization at Droplet Interfaces.  J. Am. Chem. Soc.   2022, 144, 22059-22066.  DOI: 10.1021/jacs.2c09346.

292. Chen, Z.; Huang, Y.; Gao, J.; Zhang, L.; Zaifei, M.; Liu, M.; Emrick, T.; Liu, Y. Synchronous Doping Effects of Cathode Interlayers on Efficient Organic Solar Cells. ACS Energy Lett, 2022, 7, 4052-4060. DOI.org/10.1021/acsenergylett.2c02153.

291. Cheng, Y.H.; Kirschner, A.Y.; Chang, C.C.; He, Z.W.; Nassr, M.; Emrick, T.; Freeman, B.D. Surface Modification of Ultrafiltration Membranes with 1,4-Benzoquinone and Polyetheramines to Improve Fouling Resistance. ACS Applied Materials & Interfaces 2022, 14(46), 52390-52401. DOI: 10.1021/acsami.2c14884

290. Cui, J.X.; Cueto, C.; Bien, C.; Preda, D.; Gamliel, D.; Emrick, T. Robust polymer foams from 2-hydroxyethyl cellulose: Fabrication, stability, and chemical functionalization. Polymer 2022, 256, Article: 125131. DOI: 10.1016/j.polymer.2022.125131

289. Zhou, L.; Emenuga, M.; Kumar, S.; Lamantia, Z.; Figueiredo, M.; Emrick, T. Designing Synthetic Polymers for Nucleic Acid Complexation and Delivery: From Polyplexes to Micelleplexes to Triggered Degradation. Biomacromolecules 2022 23(10), 4029-4040. DOI: 10.1021/acs.biomac.2c00767

288. Cueto, C.; Hu, W.G; Ribber, A.; Bolduc, K.; Emrick, T. Polystyrene-based Macromolecular Ammonium Halides for Tuning Color and Exchange Kinetics of Perovskite Nanocrystals. Angewandte Chemie-International Edition 2022, 61(37), Article: e202207126. DOI: 10.1002/anie.202207126

287. Prevost, L.; Barber, D.M.; Daieff, M.; Pham, J.T.; Crosby, A.J.; Emrick, T.; du Roure, O.; Lindner, A. Shaping Nanoscale Ribbons into Microhelices of Controllable Radius and Pitch. ACS Nano 2022, 16(7), 10581-10588. DOI: 10.1021/acsnano.2c02038

286. Zhang, Z.W.; Cueto, C.; Ding, Y.M.; Yu, L.; Russell, T.P.; Emrick, T.; Liu, Y. High-Performance 1 cm2 Perovskite-Organic Tandem Solar Cells with a Solvent-Resistant and Thickness-Insensitive Interconnecting Layer. ACS Applied Materials & Interfaces 2022, 14(26), 29896-29904. DOI: 10.1021/acsami.2c06760

285.  Hight-Huf, N.; Pagaduan, J.N.; Katsumata, R.; Emrick, T.; Barnes, M.D. Stabilization of Three-Particle Excitations in Monolayer MoS2 by Fluorinated Methacrylate Polymers. Journal of Physical Chemistry Letters 2022, 13(21), 4794-4799. DOI: 10.1021/acs.jpclett.2c01150

284.  Marin, A.A.; Decker, R.E.; Kumar, S.; Lamantia, Z.; Yokota, H.; Emrick, T.; Figueiredo, M.L. Enhancing Prednisone-Based Arthritis Therapy with Targeted IL-27 Gene Delivery. Bioengineering-Basel 2022, 9(6), Article: 248. DOI: 10.3390/bioengineering9060248

283.  Pagaduan, J.N.; Samitsu, S.; Varma, J.; Emrick, T.; Katsumata, R. Freeze-Burn: Fabrication of Porous Carbon Networks via Polymer-Templated Rapid Thermal Annealing.  ACS Applied Materials 2022 4 (6), 4329-4338.  DOI: 10-1021/acsapm.2c00283

282. Zhewei, Z.; Cueto,C.; Yiming D; Le Y; Russell, T.P.; Emrick, T.; Yao, L. High-Performance 1cm(2) Perovskite-Organic Tandem Solar Cells with a Solvent Resistant and Thickness-Insensitive Interconnecting Layer. ACS Applied Materials & Interfaces 2022, 14(26), 29896-29904.  DOI: 10:1021/acsami.2c06760

281. Prevost, L.; Barber, D.M.; Daieff, M.; Pham, J.T.; Crosby, A.J.; Emrick, T.; du Roure, O.; Lindner, A. Shaping Nanoscale Ribbons into Microhelices of Controllable Radius and Pitch. ACS Nano 2022, 16(7), 10581-10588. DOI: 10.1021/acsnano.2c02038

280. Margossian, K.O.; Brown, M.U.; Emrick, T.; Muthukumar, M. Coacervation in polyzwitterion-polyelectrolyte systems and their potential applications for gastrointestinal drug delivery platforms. Nature Communications 2022, 13(1), Article: 2250. DOI: 10.1038/s41467-022-29851-y

279. Chen, Z.; Hu, M.Q.; Li, X.D.; Smith, D.M.; Seong, H.G.; Emrick, T.; Rzayev, J.; Russell, T.P. In Situ Hydrolysis of Block Copolymers at the Water-Oil Interface. Angewandte Chemie-International Edition 2022, Article e202201392. DOI: 10.1002/anie.202201392

278. Cueto, C.; Donaghue, C.; Bolduc, K.; Emrick, T. Zwitterion Block Copolymers for the Synthesis and Stabilization of Perovskite Nanocrystals. Chemistry-A European Journal 2022, 28(30), Article: e202200409. DOI: 10.1002/chem.202200409

277. Seong, H.G.; Chen, Z.; Emrick, T.; Russell, T.P. Reconfiguration and Reorganization of Bottlebrush Polymer Surfactants. Angewandte Chemie-International Edition 2022, 61(19), Article: e202200530. DOI: 10.1002/anie.202200530

276. Brown, M.U.; Seong, H.G.; Margossian, K.O.; Bishop, L.; Russell, T.P.; Muthukumar, M.; Emrick, T. Zwitterionic Ammonium Sulfonate Polymers: Synthesis and Properties in Fluids. Macromolecular Rapid Communications 2022 43(12), Article: 2100678. DOI: 10.1002/marc.202100678


275. Figueiredo, M.L.; Letteri, R.; Chan-Seng, D.; Kumar, S.; Rivera-Cruz, C.M.; Emrick, T.S. Reengineering Tumor Microenvironment with Sequential Interleukin Delivery. Bioengineering-Basel 2021, 8(7), Article: 90. DOI: 10.3390/bioengineering8070090

274. Zhou, L.; Triozzi, A.; Figueiredo, M.; Emrick, T. Fluorinated Polymer Zwitterions: Choline Phosphates and Phosphorylcholines. ACS Macro Letters 2021, 10(10), 1204-1209. DOI: 10.1021/acsmacrolett.1c00451

273. Hight-Huf, N.; Nagar, Y.; Levi, A.; Pagaduan, J.N.; Datar, A.; Katsumata, R.; Emrick, T.; Ramasubramaniam, A.; Naveh, D.; Barnes, M.D. Polarization-Driven Asymmetric Electronic Response of Monolayer Graphene to Polymer Zwitterions Probed from Both Sides. ACS Applied Materials & Interfaces 2021, 13(40), 47945-47953. DOI: 10.1021/acsami.1c13505

272. Yang, Z.F.; Zhao, J.; Emrick, T. Functional Polymer Zwitterions as Reactive Surfactants for Nanoparticle Capture. ACS Applied Materials & Interfaces 2021, 13(18), 21898-21904. DOI: 10.1021/acsami.1c05955

271. Brown, M.U.; Triozzi, A.; Emrick, T. Polymer Zwitterions with Phosphonium Cations. Journal of the American Chemical Society 2021, 143(17), 6528-6532. DOI: 10.1021/jacs.1c00793

270. Kim, H.; Sundaram, S.; Kang, J.H.; Tanjeem, N.; Emrick, T.; Hayward, R.C. Coupled oscillation and spinning of photothermal particles in Marangoni optical traps. Proceedings of the National Academy of Sciences of the United States of America 2021, 118(18), Article: e2024581118, 9 pages. DOI: 10.1073/pnas.2024581118

269. Zhao, J.; Pan, Z.H.; Snyder, D.; Stone, H.A.; Emrick, T. Chemically Triggered Coalescence and Reactivity of Droplet Fibers. Journal of the American Chemical Society 2021, 143(14), 5558-5564. DOI: 10.1021/jacs.1c02576

268. Sun, Y.L.; Montz, B.J.; Selhorst, R.; Tang, H.Y.; Zhu, J.X.; Nevin, K.P.; Woodard, T.L.; Ribbe, A.E.; Russell, T.P.; Nonnenmann, S.S.; Lovley, D.R.; Emrick, T. Solvent-Induced Assembly of Microbial Protein Nanowires into Superstructured Bundles. Biomacromolecules 2021, 22(3), 1305-1311. Article: e2024581118. DOI: 10.1021/acs.biomac.0c01790

267. Pagaduan, J.N.; Hight-Hug, N.; Datar, A.; Nagar, Y.; Barnes, M.; Naveh, D.; Ramasubramaniam, A.; Katsumata, R.; Emrick, T. Electronic Tuning of Monolayer Graphene with Polymeric “Zwitterists.” ACS Nano 2021, 15(2), 2762-2770. Article: e2024581118. DOI: 10.1021/acsnano.0c08624


Zhang, Z.W.; Sheri, M.; Page, Z.A.; Emrick, T.; Saeki, A.; Liu, Y.; Russell, T.P. Understanding Hole Extraction of Inverted Perovskite Solar Cells. ACS Applied Materials & Interfaces 2020, 12(50), 56068-56075. DOI: 10.1021/acsami.0c18108

Saraf, C.; Stubbs, E.; Hu, W.G.; Emrick, T.; Lesser, A.J. Combining Mechanical Fortification and Ultralow Flammability in Epoxy Networks. Macromolecular Materials and Engineering 2020, Early Access Nov 2020, Article 2000567, 9 pages. DOI: 10.1002/mame.202000567

Liu, Y.L.; Santa Chalarca, C.F.; Carmean, R.N.; Olson, R.A.; Madinya, J.; Sumerlin, B.S.; Sing, C.E.; Emrick, T.; Perry, S.L. Effect of Polymer Chemistry on the Linear Viscoelasticity of Complex Coacervates. Macromolecules 2020, 53(18), 7851-7864. DOI: 10.1021/acs.macromol.0c00758

Zhao, J.; Santa Chalarca, C.F.; Nunes, A.K.; Stone, H.A.; Emrick, T. Self-Propelled Supracolloidal Fibers from Multifunctional Polymer Surfactants and Droplets. Macromolecular Rapid Communications 2020, 41(15), Article 2000334, 7 pages. DOI: 10.1002/marc.202000334

Barber, D.M.; Yang, Z.F.; Prevost, L.; du Roure, O.; Lindner, A.; Emrick, T.; Crosby, A.J. Programmed Wrapping and Assembly of Droplets with Mesoscale Polymers. Advanced Functional Materials 2020, 30(36), Article 2002704, 9 pages. DOI: 10.1002/adfm.202002704

Figueiredo, M.L.; Neto, M.F.; Salameh, J.W.; Decker, R.E.; Letteri, R.; Chan-Seng, D.; Emrick, T. Ligand-Mediated Targeting of Cytokine Interleukin-27 Enhances Its Bioactivity in Vivo. Molecular Therapy-Methods & Clinical Development 2020, 17, 739-751. DOI: 10.1016/j.omtm.2020.03.022

Smith, A.F.; Liu, X.M.; Woodard, T.L; Fu, T.D.; Emrick, T.; Jimenez, J.M.; Lovley, D.R.; Yao, J. Bioelectronic protein nanowire sensors for ammonia detection. Nano Research 2020, 13(5), 1479-1484. DOI: 10.1007/s12274-020-2825-6

Kim, H.; Hight-Huf, N.; Kang, J.H.; Bisnoff, P.; Sundararajan, S.; Thompson, T.; Barnes, M.; Hayward, R.C.; Emrick, T. Polymer Zwitterions for Stabilization of CsPbBr3 Perovskite Nanoparticles and Nanocomposite Films. Angeqandte Chemie-International Edition 2020, 59(27), 10802-10806. DOI: 10.1002/anie.201916492

Wu, Y.; Liu, Y.; Emrick, T.; Russell, T.P. Polymer design to promote low work function surfaces in organic electronics. Progress In Polymer Science 2020, 103, Article 101222, 11 pages. DOI: 10.1016/j.progpolymsci.2020.101222

Salameh, J.W.; Zhou, L.; Ward, S.M.; Santa Chalarca, C.F.; Emrick, T.; Figueiredo, M.L. Polymer-mediated gene therapy: Recent advances and merging of delivery techniques. Wiley Interdisciplinary Reviews - Nanomedicine and Nanobiotechnology 2020, DOI: 10.1002/wnan.1598


Wang, J.Y.; Chen, W.; Nagao, M.; Shelat, P.; Hammer, B.A.G.; Tietjen, G.T.; Cao, K.D.; Henderson, J.M.; He, L.L.; Lin, B.; Akgun, B.; Meron, M.; Qian, S.; Ward, S.; Marks, J.D.; Emrick, T.; Lee, K.Y.C. Tailoring Biomimetic Phosphorylcholine-Containing Block Copolymers as Membrane-Targeting Cellular Rescue Agents. Biomacromolecules 2019, 20(9), 3385-3391. DOI: 10.1021/acs.biomac.9b00621

Stubbs, E.; Brown, M.; Steele, A.; Song, C.; Emrick, T. Designing branched deoxybenzoin polyesters and polymeric flame retardants. Journal of Polymer Science Part A-Polymer Chemistry 2019, 57(16), 17645-1770. DOI: 10.1002/pola.29446

Kim, H.; Kang, J.H.; Zhou, Y.; Kuenstler, A.S.; Kim, Y.; Chen, C.; Emrick, T.; Hayward, R.C. Light-driven shape morphing, assembly, and motion of nanocomposite gel surfers. Advanced Materials 2019, 31 (27), Article 1900932, 7 pages. DOI: 10.1002/adma.201900932

Liu, Y.; Sheri, M.; Cole, M.D.; Yu, D.M.; Emrick, T.; Russell, T.P. Transforming Ionene Polymers into Efficient Cathode Interlayers with Pendent Fullerenes. Angewandte Chemie-International Edition 2019, 58 (17), 5677-5681. DOI: 10.1002/anie.201901536

Li, Y.; Cole, M.D.; Gao, Y.G.; Emrick, T.; Xu, Z.; Liu, Y.; Russell, T.P. High-Performance Perovskite Solar Cells with a Non-doped Small Molecule Hole Transporting Layer. ACS Applied Energy Materials 2019, 2 (3), 1634-1641. DOI: 10.1021/acsaem.9b00164

Kim, H.; So, S.; Ribbe, A.; Liu, Y.; Hu, W.; Duzhko, V.V.; Harward, R.C.; Emrick, T.  Functional polymers for growth and stabilization of CsPbBr3 perovskite nanoparticles.  Chemical Communications 2019, 55 (12), 1833-1836.  DOI: 10.1039/c8cc09343a

Sathyan, A.; Yang, Z.F.; Bai, Y.; Kim, H.; Crosby, A.; Emrick, T.  Simultaneous "Clean-and-Repair" of Surfaces Using Smart Droplets.  Advanced Functional Materials 2019, 29 (5), Article 1805219, 6 pages.  DOI: 10.1002/adfm.201805219

Wang, P.J.; Selhorst, R.; Emrick, T.; Ramasubramaniam, A.; Barnes, M.D.  Bidirectional Electronic Tuning of Single-Layer MoS2 with Conjugated Organochalcogens.  Journal of Physical Chemistry C 2019, 123 (2), 1506-1511.  DOI: 10.1021/acs.jpcc.8b10826

Sathyan, A.; Hayward, R.C.; Emrick T.  Ring-Opening Polymerization of Allyl-Functionalized Lactams.  Macromolecules 2019, 52 (1), 167-175.  DOI: 10.1021/acs.macromol.8b02148


Ly, J.T.; Burnett, E.K.; Thomas, S.; Aljarb, A.; Liu, Y.; Park, S.; Rosa, S; Yi, Y.; Lee, H.; Emrick, T.; Russell, T.P.; Bredas, J.L.; Briseno, A.L.  Efficient Electron Mobility in an All-Acceptor Napthalenediimide-Bithiazole Polymer Semiconductor with Large Backbone Torsion.  ACS Applied Materials & Interfaces 2018, 10 (46), 40070-40077.  DOI: 10.1021/acsami.8b11234

Santa Chalarca, C.F.; Letteri, R.A.; Perazzo, A.; Stone, H.A.; Emrick, T.  Building supracolloidal fibers from zwitterion-stabilized adhesive emulsions.  Advanced Functional Materials 2018, 28(45), Article 1804325, 10 pages. DOI: 10.1002/adfm.201804325

Sun, Y.L.; Tang, H.Y.; Ribbe, A.; Duzhko, V.; Woodard, T.L.; Ward, J.E.; Bai, Y.; Nevin, K.P.; Nonnenmann, S.S.; Russell, T.; Emrick, T.; Lovley, D.R.  Conductive composite materials fabricated from microbially produced protein nanowires.  Small 2018, 14 (44), Article 1802624, 5 pages.  DOI: 10.1002/smll.201802624

Ward, S.M.; Skinner, M.; Saha, B.; Emrick, T.  Polymer -  Temozolomide conjugates as therapeutics for treating Glioblastoma.  Molecular Pharmaceutics 2018, 15 (11), 5263-5276. DOI: 10.1021/acs.molpharmaceut.8b00766

Karak, S.; Page, Z.A.; Li, S.G.; Tinkham, J.S.; Lahti, P.M.; Duzhko, V.V.; Emrick, T.  Amino-fulleropyrrolidines as electrotropic additives to enhance organic photovoltaics.  Sustainable Energy & Fuels 2018, 2(10), 2143-2147.  DOI: 10.1039/c8se00294k

Skinner, M.; Johnston, B.M.; Liu, Y.L.; Hammer, B.; Selhorst, R.; Xenidou, I.; Perry, S.L.; Emrick, T.  Synthesis of Zwitterionic Pluronic Analogs. Biomacromolecules 2018, 19(8), 3377-3389.  DOI: 10.1021/acs.biomac.8b00676

Liu, Y.; Sheri, M.; Cole, M.D.; Emrick, T.; Russell, T.P.  Combining Fullerenes and Zwitterions in Non-Conjugated Polymer Interlayers to Raise Solar Cell Efficiency.  Angewandte Chemie-International Edition 2018, 57 (31), 9675-9678.  DOI: 10.1002/anie.201803748

Heo, K.; Miesch, C.; Na, J.H.; Emrick, T.; Hayward, R.C.  Assembly of P3HT/CdSe nanowire networks in an insulating polymer host.  Soft Matter 2018, 14 (25), 5327-5332.  DOI: 10.1039/c8sm01001c

Jansen, L.E.; Amer, L.D.; Chen, E.Y.UT.; Nguyen, T.V.; Saleh, L.S.; Emrick, T.; Liu, W.F.; Bryant, S.J.; Peyton, S.R.  Zwitterionic PEG-PC Hydrogels Modulate the Foreign Body Response in a Modulus-Dependent Manner.  Biomacromolecules 2018, 19 (7), 2880-2888.  DOI: 10.1021/acs.biomac.8b00444

Selhorst, R.; Wang, P.J.; Barnes, M.; Emrick, T.  Bithiazolidinyleidene polymers: synthesis and electronic interactions with transition metal dichalcogenides.  Chemical Science 2018, 9 (22), 5047-5051.  DOI: 10.1039/c8sc01416g

Forth, J.; Liu, X.B.; Hasnain, J.; Toor, A.; Miszta, K.; Shi, S.W.; Geissler, P.L.; Emrick, T.; Helms, B.A.; Russell, T.P. Reconfigurable Printed Liquids. Advanced Materials 2018, 30(16). artno. 1707603. DOI: 10.1002/adma.201707603

Sheri, M.; Choudhary, U.; Grandhee, S.; Emrick, T. Fluoride-Catalyzed Deblocking: A Route to Polymeric Urethanes. Angewandte Chemie-International Edition 2018, 57(17), 4599-4602. DOI: 10.1002/anie.201800795

Liu, Y.; Cole, M.D.; Jiang, Y.F.; Kim, P.Y.; Nordlund, D.; Emrick, T.; Russell, T.P.  Chemical and Morphological Control of Interfacial Self-Doping for Efficient Organic Electronics. Advanced Materials 2018, 30 (15), Article 1705976, 8 pages.  DOI: 10.1002/adma.201705976

Barber, D.; Crosby, A.J.; Emrick, T.  Mesoscale block copolymers. Advanced Materials 2018, 30 (13), Article 1706118, 6 pages. DOI: 10.1002/adma.201706118

Liu, Y.; Page, Z.A.; Zhou, D.M.; Duzhko, V.V.; Kittilstved, K.R.; Emrick, T.; Russell, T.P.  Chemical Stabilization of Perovskite Solar Cells with Functional Fulleropyrrolidines.  ACS Central Science 2018, 4 (2), 216-222.  DOI: 10.1021/acscentsci.7b00454

Alon, H.; Stern, C.; Kirshner, M.; Sinai, O.; Wasserman, M.; Selhorst, R.; Gasper, R.; Ramasubramaniam, A.; Emrick, T.; Nayeh, D. Lithographically Patterned Functional Polymer-Graphene Hybrids for Nanoscale Electronics. ACS Nano 2018, 12 (2), 1928-1933. DOI: 10.1021/acsnano.7b08844

Skinner, M.; Ward, S.M.; Nilsson, C.L.; Emrick, T.  Augmenting Glioblastoma Chemotherapy with Polymers.  ACS Chemical Neuroscience 2018, 9 (1), 8-10.  DOI: 10.1021/acschemneuro.7b00168


Tran, Y.H.; Rasmuson, M.J.; Emrick, T.; Klier, J.; Peyton, S.R.  Strain-stiffening gels based on latent crosslinking. Soft Matter 2017, 13 (47), 9007-9014. DOI: 10.1039/c7sm01888f

Kalasin, S.; Letteri, R.A.; Emrick, T.; Santore, MM.  Adsorbed Polyzwitterion Copolymer Layers Designed for Protein Repellency and Interfacial Retention.  Lanmuir 2017, 33 (47), 13708-13717.  DOI: 10.1021/acs.langmuir.7b03391

Ramasubramanium, A.; Selhorst, R.; Alon, H.; Barnes, M.D.; Emrick, T.; Naveh, D. Combining 2D inorganic semiconductors and organic polymers at the frontier of the hard-soft materials interface. Journal of Materials Chemistry C 2017, 5 (43), 11158-11164.DOI: 10.1039/c7tc02790g 

Liu, Y.; Renna, L.A.; Thompson, H.B.; Page, Z.A.; Emrick, T.; Barnes, M.D.; Bag, M.; Venkataraman, D.; Russell, T.P. Role of Ionic Functional Groups on Ion Transport at Perovskite Interfaces. Advanced Energy Materials 2017, 7 (21), Article 1701235, 13 pages. DOI: 10.1002/aenm.201701235

Ruscello, M.; Stolz, S.; Arellano, D.L.G.; Ullrich, F.; Hillebrandt, S.; Mankel, E.; Pucci, A.; Kowalsky, W.; Emrick, T.; Briseno, A.L.; Hernandez-Sosa, G. Electron injection and interfacial trap passivation in solution-processed organic light-emitting diodes using a polymer zwitterion interlayer. Organic Electronics 2017, 50, 384-388. DOI: 10.1016/j.orgel.2017.08.014

Kirschner, A.Y.; Chang, C.C.; Kasemset, S.; Emrick, T.; Freeman, B.D. Fouling-resistant ultrafiltration membranes prepared via co-deposition of dopamine/zwitterion composite coatings. Journal of Membrane Science 2017, 541, 300-311. DOI: 10.1016/j.memsci.2017.06.055

Letteri, R.A.; Chalarca, C.F.S.; Bai, Y.; Hayward, R.C.; Emrick, T. Forming Sticky Droplets from Slippery Polymer Zwitterions. Advanced Materials 2017, 29 (38), Article 1702921, 8 pages. DOI: 10.1002/adma.201702921

Cole, M.D.; Sheri, M.; Bielicki, C.; Emrick, T. Perylene Diimide-Based Ionene and Zwitterionic Polymers: Synthesis and Solution Photophysical Properties. Macromolecules 2017, 50 (19), 7535-7542. DOI: 10.1021/acs.macromol.7b01281

Wang, J.C.; Bindokas, V.P.; Skinner, M.; Emrick, T.; Marks, J.D. Mitochondrial mechanisms of neuronal rescue by F-68, a hydrophilic Pluronic block co-polymer, following acute substrate deprivation. Neurochemistry International 2017, 109 (Special Issue), 126-140. DOI: 10.1016/j.neuint.2017.04.007

Johnston, B.M.; Johnston, C.W.; Letteri, R.A.; Lytle, T.K.; Sing, C.E.; Emrick, T.; Perry, S.L. The effect of comb architecture on complex coacervation. Organic & Biomolecular Chemistry 2017, 15 (36), 7630-7642. DOI: 10.1039/c7ob01314k

Sae-Ung, P.; Kolewe, K. W.; Bai, Y.; Rice, E. W.; Schiffman, J. D.; Emrick, T.; Hoven, V. P.  Antifouling Stripes Prepared from Clickable Zwitterionic Copolymers.  Langmuir 2017, 33 (28), 7028-7035.  DOI: 10.1021/acs.langmuir.7b01431

Choudhary, U.; Mir, A. A.; Emrick, T.  Soluble, Allyl-Functionalized Deoxybenzoin Polymers.  Macromolecules 2017, 50 (10), 3773-3779.  DOI: 10.1021/acs.macromol.7b00460

Duzhko, V. V.; Dunham, B.; Rosa, S. J.; Cole, M. D.; Paul, A.; Page, Z. A.; Dimitrakopoulos, C.; Emrick, T.  N-Doped Zwitterionic Fullerenes as Interlayers in Organic and Perovskite Photovoltaic Devices.  ACS Energy Letters 2017, 2 (5), 957-963.  DOI: 10.1021/acsenergylett.7b00147

Skinner, M.; Ward, S. M.; Emrick, T.  Versatile Synthesis of Polymer-Temozolomide Conjugates.  ACS Macro Letters 2017, 6 (3), 215-218.  DOI: 10.1021/acsmacrolett.7b00007

Kosif, I.; Kratz, K.; You, S. S.; Bera, M. K.; Kim, K.; Leahy, B.; Emrick, T.; Lee, K. Y. C.; Lin, B. H.  Robust Gold Nanoparticle Sheets by Ligand Cross-Linking at the Air-Water Interface.  ACS Nano 2017, 11 (2), 1292-1300.  DOI: 10.1021/acsnano.6b05563

Chalarca, C. F. S.; Emrick, T., Reactive polymer zwitterions: Sulfonium sulfonates. Journal of Polymer Science Part A-Polymer Chemistry 2017, 55 (1), 83-92. DOI: 10.1002/pola.28359.


Bai, Y.; Chang, C. C.; Choudhary, U.; Bolukbasi, I.; Crosby, A. J.; Emrick, T., Functional droplets that recognize, collect, and transport debris on surfaces. Science Advances 2016, 2 (10), e1601462. DOI: 10.1126/sciadv.1601462.

Bai, Y.; Chang, C. C.; Zhao, X. J.; Ribbe, A.; Bolukbasi, I.; Szyndler, M. J.; Crosby, A. J.; Emrick, T. Mechanical Restoration of Damaged Polymer Films by "Repair-and-Go". Advanced Functional Materials 2016, 26(6), 857-863. DOI: 10.1002/adfm.201503947

Chang, C. C.; Kolewe, K. W.; Li, Y. Y.; Kosif, I.; Freeman, B. D.; Carter, K. R.; Schiffman, J. D.; Emrick, T. Underwater Superoleophobic Surfaces Prepared from Polymer Zwitterion/Dopamine Composite Coatings. Advanced Materials Interfaces 2016, 3(6), Article 1500521, 9 pages. DOI: 10.1002/admi.201500521

Ghobadi, A. F.; Letteri, R.; Parelkar, S. S.; Zhao, Y.; Chan-Seng, D.; Emrick, T.; Jayaraman, A. Dispersing Zwitterions into Comb Polymers for Nonviral Transfection: Experiments and Molecular Simulation. Biomacromolecules 2016, 17(2), 546-557. DOI: 10.1021/acs.biomac.5b01462

Hu, G. J.; Emrick, T. Functional Choline Phosphate Polymers. Journal of the American Chemical Society 2016, 138 (6), 1828-1831. DOI: 10.1021/jacs.5b13156

Kolewe, K. W.; Dobosz, K. M.; Rieger, K. A.; Chang, C. C.; Emrick, T.; Schiffman, J. D., Antifouling Electrospun Nanofiber Mats Functionalized with Polymer Zwitterions. ACS Applied Materials & Interfaces 2016, 8 (41), 27585-27593. DOI: 10.1021/acsami.6b09839.

Lawrence, J.; Emrick, T. Pentafluorophenyl Ester-Functionalized Nanoparticles as a Versatile Platform for Selective and Covalent Inter-nanoparticle Coupling. ACS Applied Materials & Interfaces 2016, 8(3), 2393-2398. DOI: 10.1021/acsami.5b11550

Lee, H.; Stephenson, J. C.; Richter, L. J.; McNeill, C. R.; Gann, E.; Thomsen, L.; Park, S.; Jeong, J.; Yi, Y.; DeLongchamp, D. M.; Page, Z. A.; Puodziukynaite, E.; Emrick, T.; Briseno, A. L. The Structural Origin of Electron Injection Enhancements with Fulleropyrrolidine Interlayers. Advanced Materials Interfaces 2016, 3(10), Article 1500852, 7 pages. DOI: 10.1002/admi.201500852

Liu, Y.; Duzhko, V. V.; Page, Z. A.; Emrick, T.; Russell, T. P., Conjugated Polymer Zwitterions: Efficient Interlayer Materials in Organic Electronics. Accounts of Chemical Research 2016, 49 (11), 2478-2488. DOI: 10.1021/acs.accounts.6b00402.

Liu, Y.; Bag, M.; Renna, L. A.; Page, Z. A.; Kim, P.; Emrick, T.; Venkataraman, D.; Russell, T. P. Understanding Interface Engineering for High-Performance Fullerene/Perovskite Planar Heterojunction Solar Cells. Advanced Energy Materials 2016, 6(2), Article 1501606, 7 pages. DOI: 10.1002/aenm.201501606

Liu, Y.; Renna, L. A.; Page, Z. A.; Thompson, H. B.; Kim, P. Y.; Barnes, M. D.; Emrick, T.; Venkataraman, D.; Russell, T. P., A Polymer Hole Extraction Layer for Inverted Perovskite Solar Cells from Aqueous Solutions. Advanced Energy Materials 2016, 6 (20), 1600664. DOI: 10.1002/aenm.201600664.

Liu, Y.; Renna, L. A.; Bag, M.; Page, Z. A.; Kim, P.; Choi, J.; Emrick, T.; Venkataraman, D.; Russell, T. P. High Efficiency Tandem Thin-Perovskite/Polymer Solar Cells with a Graded Recombination Layer. ACS Applied Materials & Interfaces 2016, 8(11), 7070-7076. DOI: 10.1021/acsami.5b12740

Mir, A. A.; Wagner, S.; Kramer, R. H.; Deglmann, P.; Emrick, T. Deoxybenzoin-containing polysulfones and polysulfoxides: Synthesis and thermal properties. Polymer 2016, 84, 59-64. DOI: 10.1016/j.polymer.2015.12.031

Morozova, S.; Hu, G.; Emrick, T.; Muthukumar, M. Influence of Dipole Orientation on Solution Properties of Polyzwitterions. ACS Macro Letters 2016, 5(1), 118-122. DOI: 10.1021/acsmacrolett.5b00876

Page, Z. A.; Liu, Y.; Puodziukynaite, E.; Russell, T. P.; Emrick, T. Hydrophilic Conjugated Polymers Prepared by Aqueous Horner-Wadsworth-Emmons Coupling. Macromolecules 2016, 49(7), 2526-2532. DOI: 10.1021/acs.macromol.5b02501

Selhorst, R. C.; Puodziukynaite, E.; Dewey, J. A.; Wang, P.; Barnes, M. D.; Ramasubramaniam, A.; Emrick, T. Tetrathiafulvalene-containing polymers for simultaneous non-covalent modification and electronic modulation of MoS2nanomaterials. Chemical Science 2016, 7(7), 4698-4705. DOI: 10.1039/c6sc00305b

Skinner, M.; Selhorst, R.; Emrick, T. Synthesis of Water-Soluble Zwitterionic Polysiloxanes. Journal of Polymer Science Part A-Polymer Chemistry 2016, 54(1), 127-134. DOI: 10.1002/pola.27773

Wong, K. E.; Mora, M. C.; Skinner, M.; Page, S. M.; Crisi, G. M.; Arenas, R. B.; Schneider, S. S.; Emrick, T. Evaluation of PolyMPC-Dox Prodrugs in a Human Ovarian Tumor Model. Molecular Pharmaceutics 2016, 13(5), 1679-1687. DOI: 10.1021/acs.molpharmaceut.6b00092


Chang, CC., Letteri, R., Hayward, RC., Emrick, T. “Functional sulfobetaine polymers: Synthesis and salt-responsive stabilization of oil-in-water droplets” Macromolecules, 2015, 48, 7843-7850. DOI: 10.1021/acs.macromol.5b01861

Chen, DY., Chang, CC., Cooper, B., Silvers, A., Emrick T., Hayward, RC. “Photopatternable biodegradable aliphatic polyester with pendent benzophenone groups” Biomacromolecules, 2015, 16, 3329-3335. DOI: 10.1021/acs.biomac.5b00991

Liu, YJ., Chen, YC., Hutchens, S., Lawrence, J., Emrick, T., Crosby, AJ. “Directly measuring the complete stress-strain response of ultrathin polymer films” Macromolecules, 2015, 48, 6534-6540. DOI: 10.1021/acs.macromol.5b01473

Liu, Y., Page, ZA., Russell, TP., Emrick, T. “Finely tuned polymer interlayers enhance solar cell efficiency” Angewandte Chemie-International Edition, 2015, 54, 11485-11489. DOI: 10.1002/anie.201503933

Kim, HJ., Skinner, M., Yu, H., Oh, JH., Briseno, AL., Emrick, T., Kim, BJ., Haryward, RC. “Water processable polythiophene nanowires by photo-cross-linking and click-functionalization” Nano Letters, 2015, 15, 5689-5695. DOI: 10.1021/acs.nanolett.5b01185

Liu, Y., Page, Z., Ferdous, S., Liu, F., Kim, P., Emrick, T., Russell, T. “Dual functional zwitterionic fullerene interlayer for efficient inverted polymer solar cells” Advanced Energy Materials, 2015, 5.  DOI: 10.1002/aenm.201500405

Neto, MF., Letteri, R., Chan-Seng, D., Emrick, T., Figueiredo, ML. “Sonodelivery facilitates sustained luciferase expression from an episomal vector in skeletal muscle” Materials, 2015, 8, 4608-4617. DOI: 10.3390/ma8074608

Acevedo-Cartagena, DE., Zhu, JX., Trabanino, E., Pentzer, E., Emrick, T., Nonnenmann, SS., Briseno, AL., Hayward, RC. “Selective nucleation of poly(3-hexyl thiophene) nanofibers on multilayer graphene substrates” ACS Macro Letters, 2015, 4, 483-487. DOI: 10.1021/acsmacrolett.5b00038

Karak, S., Page, ZA., Tinkham, JS., Lahti, PM., Emrick, T., Duzhko, VV. “Raising efficiency of organic solar cells with electrotropic additives” Applied Physics Letters, 2015, 106. DOI: 10.1063/1.4914847

Page, ZA., Liu, F., Russell, TP., Emrick, T. “Tuning the energy gap of conjugated polymer zwitterions for efficient interlayers and solar cells” Journal of Polymer Science Part A-Polymer Chemistry, 2015, 53, 327-336. DOI: 10.1002/pola.27349

Lee, H., Puodziukynaite, E., Zhang, Y., Stephenson, JC., Richter, LJ., Fischer, DA., DeLongchamp, DM., Emrick, T., Briseno, AL. “Poly(sulfobetaine methacrylate)s as electrode modifiers for inverted organic electronics” Journal of the American Chemical Society, 2015, 137, 540-549. DOI: 10.1021/ja512148d

Hu, GJ., Parelkar, SS., Emrick, T. “A facile approach to hydrophilic, reverse zwitterionic, choline phosphate polymers” Polymer Chemistry, 2015, 6, 525-530. DOI: 10.1039/c4py01292e


Baghgar, M., Barnes, A.M., Pentzer, E., Wise, A.J., Hammer, B.A.G., Emrick, T., Dinsmore, A.D. and Barnes, M.D. Morphology-Dependent Electronic Properties in Cross-Linked (P3HT-b-P3MT) Block Copolymer Nanostructures. ACS Nano, 2014, 8(8): 8344-8349. DOI: 10.1021/nn502806d

Carnis, J., Cha, W., Wingert, J., Kang, J., Jiang, Z., Song, S., Sikorski, M., Robert, A., Gutt, C., Chen, S.-W., Dai, Y., Ma, Y., Guo, H., Lurio, L.B., Shpyrko, O., Narayanan, S., Cui, M., Kosif, I., Emrick, T., Russell, T.P., Lee, H.C., Yu, C.-J., Gruebel, G., Sinha, S.K. and Kim, H. Demonstration of Feasibility of X-Ray Free Electron Laser Studies of Dynamics of Nanoparticles in Entangled Polymer Melts. Scientific Reports, 2014, 4. DOI: 10.1038/srep06017

Chang, C.-C. and Emrick, T. Functional Polyolefins Containing Disulfide and Phosphoester Groups: Synthesis and Orthogonal Degradation. Macromolecules, 2014, 47(4): 1344-1350. DOI: 10.1021/ma500121a

Chantarak, S., Liu, F., Emrick, T. and Russell, T.P. Solvent-Assisted Orientation of Poly(3-hexylthiophene)-Functionalized CdSe Nanorods Under an Electric Field. Macromolecular Chemistry and Physics, 2014, 215(17): 1647-1653. DOI: 10.1002/macp.201400188

Ellis, J., Falzon, M., Emrick, T. and Figueiredo, M.L. Imaging Cytokine Targeting to the Tumor/Bone Microenvironment In Vivo. Human Gene Therapy Clinical Development, 2014, 25(4): 200-201.

DOI: 10.1089/humc.2014.085

Hammer, B.A.G., Reyes-Martinez, M.A., Bokel, F.A., Liu, F., Russell, T.P., Hayward, R.C., Briseno, A.L. and Emrick, T. Reversible, Self Cross-Linking Nanowires from Thiol-Functionalized Polythiophene Diblock Copolymers. ACS Applied Materials & Interfaces, 2014, 6(10): 7705-7711. DOI: 10.1021/am500976w

Hammer, B.A.G., Reyes-Martinez, M.A., Bokel, F.A., Liu, F., Russell, T.P., Hayward, R.C., Briseno, A.L. and Emrick, T. Robust polythiophene nanowires cross-linked with functional fullerenes. Journal of Materials Chemistry C, 2014, 2(45): 9674-9682. DOI: 10.1039/c4tc01898b

Kosif, I., Chang, C.C., Bai, Y., Ribbe, A.E., Balazs, A.C. and Emrick, T. Picking up Nanoparticles with Functional Droplets. Advanced Materials Interfaces, 2014, 1(5). DOI: 10.1002/admi.201400121

Lawrence, J., Pham, J.T., Lee, D.Y., Liu, Y., Crosby, A.J. and Emrick, T. Highly conductive ribbons prepared by stick-slip assembly of organosoluble gold nanoparticles. ACS Nano, 2014, 8(2), 1173-1179. DOI: 10.1021/nn4057726.

Lee, C.H., Crosby, A.J., Emrick, T. and Hayward, R.C. Characterization of heterogeneous polyacrylamide hydrogels by tracking of single quantum dots. Macromolecules, 2014, 47(2), 741-749. DOI: 10.1021/ma402373s.

Lee, C.H., Crosby, A.J., Hayward, R.C. and Emrick, T. Patterning nanoparticles into rings by "2-D pickering emulsions". ACS Applied Materials & Interfaces, 2014, 6(7), 4850-4855. DOI: 10.1021/am405828a.

Maiz, J., Zhao, W., Gu, Y., Lawrence, J., Arbe, A., Alegria, A., Emrick, T., Colmenero, J., Russell, T.P. and Mijangos, C. Dynamic study of polystyrene-block-poly(4-vinylpyridine) copolymer in bulk and confined in cylindrical nanopores. Polymer, 2014, 55(16): 4057-4066. DOI: 10.1016/j.polymer.2014.05.042

McRae Page, S., Henchey, E., Chen, X., Schneider, S. and Emrick, T. Efficacy of polyMPC-DOX prodrugs in 4T1 tumor-bearing mice. Molecular Pharmaceutics, 2014, 11(5): 1715-1720. DOI: 10.1021/mp500009r

Miesch, C. and Emrick, T. Photo-sensitive ligands on nanoparticles for achieving triggered emulsion inversion. Journal of Colloid and Interface Science, 2014, 425: 152-158. DOI: 10.1016/j.jcis.2014.03.036

Page, S.M., Henchey, E., Chen, X., Schneider, S. and Emrick, T. Efficacy of PolyMPC-DOX Prodrugs in 4T1 Tumor-Bearing Mice. Molecular Pharmaceutics, 2014, 11(5): 1715-1720. DOI: 10.1021/mp500009r

Page, S.M., Parelkar, S., Gerasimenko, A., Shin, D.Y., Peyton, S.R. and Emrick, T. Promoting cell adhesion on slippery phosphorylcholine hydrogel surfaces. Journal of Materials Chemistry B, 2014, 2(6), 620-624. DOI: 10.1039/c3tb21493a.

Page, Z.A., Liu, Y., Duzhko, V.V., Russell, T.P. and Emrick, T. Fulleropyrrolidine interlayers: Tailoring electrodes to raise organic solar cell efficiency. Science, 2014, 346(6208): 441-444. DOI: 10.1126/science.1255826

Page, Z.A., Liu, F., Russell, T.P. and Emrick, T. Rapid, facile synthesis of conjugated polymer zwitterions in ionic liquids. Chemical Science, 2014, 5(6): 2368-2373. DOI: 10.1039/c4sc00475b

Parelkar, S.S., Letteri, R., Chan-Seng, D., Zolochevska, O., Ellis, J., Figueiredo, M. and Emrick, T. Polymer-peptide delivery platforms: Effect of oligopeptide orientation on polymer-based DNA delivery. Biomacromolecules, 2014, 15(4), 1328-1336. DOI: 10.1021/bm401878p.

Pham, J.T., Lawrence, J., Grason, G.M., Emrick, T. and Crosby, A.J. Stretching of assembled nanoparticle helical springs. Physical Chemistry Chemical Physics, 2014, 16(22): 10261-10266. DOI: 10.1039/c3cp55502j

Puodziukynaite, E., Wang, H.-W., Lawrence, J., Wise, A.J., Russell, T.P., Barnes, M.D. and Emrick, T. Azulene Methacrylate Polymers: Synthesis, Electronic Properties, and Solar Cell Fabrication. Journal of the American Chemical Society, 2014, 136(31): 11043-11049. DOI: 10.1021/ja504670k

Szyndler, M.W., Timmons, J.C., Yang, Z.H., Lesser, A.J. and Emrick, T. Multifunctional deoxybenzoin-based epoxies: Synthesis, mechanical properties, and thermal evaluation. Polymer, 2014, 55(17): 4441-4446. DOI: 10.1016/j.polymer.2014.06.043

Wang, H.-W., Pentzer, E., Emrick, T. and Russell, T.P. Preparation of low band gap fibrillar structures by solvent-induced crystallization. ACS Macro Letters, 2014, 3(1), 30-34. DOI: 10.1021/mz400431s.

Zhang, Y., Diao, Y., Lee, H., Mirabito, T.J., Johnson, R.W., Puodziukynaite, E., John, J., Carter, K.R., Emrick, T., Mannsfed, S.C.B. and Briseno, A.L. Intrinsic and Extrinsic Parameters for Controlling the Growth of Organic Single-Crystalline Nanopillars in Photovoltaics. Nano Letters, 2014, 14(10): 5547-5554. DOI: 10.1021/nl501933q


Emrick, T. and Pentzer, E. Nanoscale assembly into extended and continuous structures and hybrid materials. Nature Asia Materials, 2013, 5. DOI: 10.1038/am.2012.73

Zolochevska, O., Ellis, J., Parelkar, S., Chan-Seng, D., Emrick, T., Wei, JN., Patrikeev, I., Motamedi, M., Figueiredo, ML. “Interleukin-27 gene delivery for modifying malignant interactions between prostate tumor and bone” Human Gene Therapy, 2013, 24, 970-981.  DOI: 10.1089/hum.2013.091

Pham, JT., Lawrence, J., Lee, DY., Grason, GM., Emrick, T., Crosby, AJ. “Highly stretchable nanoparticle helices through geometric asymmetry and surface forces” Advanced Materials, 2013, 25, 6703-6708.  DOI: 10.1002/adma.201302817

Liu, F., Page, ZA., Duzhko, VV., Russell, TP., Emrick, T. “Conjugated polymeric zwitterions as efficient interlayers in organic solar cells” Advanced Materials, 2013, 25, 6868-6873. DOI: 10.1002/adma.201302477

Pham, JT., Lawrence, J., Lee, DY., Grason, GM., Emrick, T., Crosby, AJ. “Nanoparticle helices: Highly stretchable nanoparticle helices through geometric asymmetry and surface forces” Advanced Materials, 2013, 25, 6635.  DOI: 10.1002/adma.201370287

Du, K., Glogowski, E., Tuominen, MT., Emrick, T., Russell, TP., Dinsmore, AD. “Self-assembly of gold nanoparticles on gallium droplets: controlling charge transport through microscopic devices” Langmuir, 2013, 29, 13640-13646.  DOI: 10.1021/la403263z

Heo, K., Miesch, C., Emrick, T., Hayward, RC. “Thermally reversible aggregation of gold nanoparticles in polymer nanocomposites through hydrogen bonding” Nano Letters, 2013, 13, 5297-5302. DOI: 10.1021/nl402813q

Cui, MM., Emrick T., Russell, TP. “Stabilizing liquid drops in nonequilibrium shapes by the iinterfacial jamming of nanoparticles” Science, 2013, 342, 460-463. DOI: 10.1126/science.1242852

Baghgar, M., Pentzer, E., Wise, AJ., Labastide, JA., Emrick, T., Barnes, MD. “Cross-linked functionalized poly(3-hexylthiophehe) nanofibers with tunable excitonic coupling” ACS Nano, 2013, 7, 8917-8923. DOI: 10.1021/nn403392b

Herrick, WG., Ngyuen, TV., Sleiman, M., McRae, S., Emrick, TS. “PEG-phosphorylcholine hydrogels as tunable and versatile platforms for mechanobiology” Biomacromolecules, 2013, 14, 2294-2304. DOI: 10.1021/bm400418g

Page, SM., Martorella, M., Parelkar, S., Kosif, I., Emrick, T. “Disulfide cross-linked phosphorylcholine micelles for triggered release of camptothecin” Molecular Pharmaceutics, 2013, 10, 2684-2692. DOI: 10.1021/mp400114n

Han, DZ., Letteri, R., Chan-Seng, D., Emrick, T., Tu, HL. “Examination of zwitterionic polymers and gels subjected to mechanical constraints” Polymer, 2013, 54, 2887-2894. DOI: 10.1016/j.polymer.2013.04.003

Moon, S., Emrick, T. “High flame resistant and strong electrospun polyacrylonitrile-carbon nanotubes-ochre nanofibers” Polymer, 2013, 54, 1813-1819.  DOI: 10.1016/j.polymer.2013.01.053

Lee, DY., Pham, JT., Lawrence, J., Lee, CH., Parkos, C., Emrick, T., Crosby, AJ. “Macroscopic nanoparticle ribbons and fabrics” Advanced Materials, 2013, 9, 1248-1253. DOI: 10.1002/adma.201203719

Laprade, EJ., Long, R., Pham, JT., Lawrence, J., Emrick, T., Crosby, AJ., Hui, CY., Shull, KR. “Large deformation and adhesive contact studies of axisymmetric membranes” Langmur, 2013, 5, 1407-1419. DOI: 10.1021/la303810d

Page, ZA., Duzhko, VV., Emrick, T. “Conjugated thiophene-containing polymer zwitterions: Direct synthesis and thin film electronic properties” Macromolecules, 2013, 2, 344-351. DOI: 10.1021/ma302232q

Chen, XJ., Lawrence, J., Parelkar, S., Emrick, T. “Novel zwitterionic copolymers with dihydrolipoic acid: Synthesis and preparation of nonfouling nanorods” Macromolecules, 2013, 1, 119-127. DOI: 10.1021/ma301288m

Kosif, I., Cui, MM., Russell, TP., Emrick, T.  “Triggered insitu disruption and inversion of nanoparticle-stabilized droplets” Angewandte Chemie-International Edition, 2013, 52, 6620-6623. DOI: 10.1002/anie.201302112


Bu, L., Pentzer, E., Bokel, F., Emrick, T., Hayward, R.  “Growth of polythiophene/perylene tetracarboxydiimide donor/acceptor shish-kebab nanostructures by coupled crystal modification” ACS Nano, 2012, 6, 10924-10929. DOI: 10.1021/nn3043836

Chen, XJ., Parelkar, S., Henchey, E., Schneider, S., Emrick, T. “PolyMPC-doxorubicin prodrugs” Bioconjugate Chemistry, 2012, 23, 1753-1763. DOI: 10.1021/bc200667s

Silvers, A., Chang, CC., Emrick, T. “Functional aliphatic polyesters and nanoparticles prepared by organocatalysis and orthogonal grafting chemistry” Journal of Polymer Science Part A – Polymer Chemistry, 2012, 50, 3517-3529. DOI: 10.1002/pola.26114

Mcrae, S, Chen, XJ., Kratz, K., Samanta, D., Henchey, E., Schneider, S., Emrick, T. “Pentafluorophenyl ester-functionalized phosphorylcholine polymers: Preparation of linear, two-arm, and grafted polymer-protein conjugates” Biomacromolecules, 2012, 13, 2099-2109. DOI: 10.1021/bm3004836

Baghgar, M., Labastide, J., Bokel, F., Dujovne, I., McKenna, A., Barnes, AM., Pentzer, E., Emrick, T., Hayward, R., Barnes, MD. “Probing inter- and intrachain exciton coupling in isolated poly(3-hexylthiophene) nanofibers: Effect of solvation and regioregularity” Journal of Physical Chemistry Letters, 2012, 3, 1674-1679. DOI: 10.1021/jz3005909

Bae, J., Lawrence, J., Miesch, C., Ribbe, A., Li, W., Emrick, T., Zhu, J., Hayward, RC. “Multifunctional nanoparticle-loaded spherical and wormlike micelles formed by interfacial instabilities” Advanced Materials, 2012, 24, 2735-2741. DOI: 10.1002/adma.201200570

Pentzer, EB., Bokel, FA., Hayward, RC., Emrick, T. “Nanocomposite ‘superhighways’ by solution assembly of semiconductor nanostructures with ligand-functionalized conjugated polymers” Advanced Materials, 2012, 24, 2254-2258. DOI: 10.1002/adma.201104788

Kratz, K., Narasimhan, A., Tangirala, R., Moon, SC., Revanu, R., Kundu, S., Kim, HS.,Crosby, AJ., Russell, TP., Emrick, T., Kolmakov, G., Balazs, AC. “Probing and repairing damaged surfaces with nanoparticle-containing microcapsules” Nature Nanotechnology, 2012, 7, 87-90. DOI: 10.1038/NNANO.2011.235

Ravichandran, S., Nagarajan, S., Ku, BC., Coughlin, B., Emrick, T., Kumar, J., Nagarajan, R. “Halogen-free ultra-high flame retardant polymers through enzyme catalysis” Green Chemistry, 2012, 14, 819-824. DOI: 10.1039/c2gc16192c

Miesch, C., Kosif, I., Lee, E., Kim, JK., Russell, TP., Hayward, RC., Emrick, T. “Nanoparticle-stabilized double emulsions and compressed droplets” Angewandte Chemie-International Edition, 2012, 51, 145-149. DOI: 10.1002/anie.201106665


Kratz, K., Xie, W., Lee, A., Freeman, BD., Emrick, T. “Phosphorylcholine-substituted ROMP polyolefin coatings provide fouling resistance to membrane materials” Macromolecular Materials and Engineering, 2011, 296, 1142-1148. DOI: 10.1002/mame.201100064

Elder, RM., Emrick, T., Jayaraman, A. “Understanding the effect of polylysine architecture on DNA binding using molecular dynamics simulations” Biomacromolecules, 2011, 12, 3870-3879. DOI: 10.1021/bm201113y

Hammer, BAG., Bokel, FA., Hayward, RC., Emrick, T. “Cross-linked conjugated polymer fibrils: Robust nanowires from functional polythiophene diblock copolymers” Chemistry of Materials, 2011, 23, 4250-4256. DOI: 10.1021/cm2018345

Ryu, BY., Emrick, T. “Bisphenol-1,2,3-triazole (BPT) epoxies and cyanate esters: Synthesis and self-catalyzed curing” Macromolecules, 2011, 44, 5693-5700. DOI: 10.1021/ma200767j

Lee, E., Hammer, B., Kim, JK., Page, Z., Emrick, T., Hayward, RC. “Hierarchical helical sssembly of conjugated poly(3-hexylthiophene)-block-poly(3-triethylene glycol thiophene) diblock copolymers” Journal of the American Chemical Society, 2011, 133, 10390-10393. DOI: 10.1021/ja2038547

Su, GM., Best, K., Ranganathan, T., Emrick, T., Crosby, AJ. “Tailored nanoparticles for enhancing polymer adhesion” Macromolecules, 2011, 44, 5256-5261. DOI: 10.1021/ma200561g

Li, L., Miesch, C., Sudeep, PK., Balazs, AC., Emrick, T., Russell, TP., Hayward, RC. “Kinetically trapped co-continuous polymer morphologies through intraphase gelation of nanoparticles” Nano Letters, 2011, 11, 1997-2003. DOI: 10.1021/nl200366z

Bokel, FA., Sudeep, PK., Pentzer, E., Emrick, T., Hayward, RC. “Assembly of poly(3-hexylthiophene)/CdSe hybrid nanowires by cocrystallization” Macromolecules, 2011, 44, 1768-1770. DOI: 10.1021/ma2003807

Parelkar, SS., Chan-Seng, D, Emrick, T. “Reconfiguring polylysine architectures for controlling polyplex binding and non-viral transfection” Biomaterials, 2011, 32, 2432-2444. DOI: 10.1016/j.biomaterials.2010.12.004

Pochan, DJ., Zhu, JH., Zhang, K., Wooley, KL., Miesch, C., Emrick, T. “Multicompartment and multigeometry nanoparticle assembly” Soft Matter, 2011, 7, 2500-2506. DOI: 10.1039/c0sm00960a


Kim, HS., Lee, CH., Sudeep, PK., Emrick, T., Crosby, A. “Nanoparticle stripes, grids, and ribbons produced by flow coating” Advanced Materials, 2010, 22, 4600-4604. DOI: 10.1002/adma.201001892

Hu, Y., Samanta, D., Parelkar, S., Hong, SW., Wang, Q., Russell, T., Emrick, T. “Ferritin-polymer conjugates: Grafting chemistry and integration into nanoscale assemblies.” Advanced Function Materials, 2010, 20, 3603-3612. DOI: 10.1002/adfm.201000958

Ryu, BY., Emrick, T. “Thermally induced structural transformation of bisphenol-1,2,3-triazole polymers: Smart, self-extinguishing materials” Angewandte Chemie-International Edition, 2010, 49, 9644-9647. DOI: 10.1002/anie.201005456

Chen, XJ., McRae, S., Samanta, D., Emrick, T. “Polymer-protein conjugation in ionic liquids” Macromolecules, 2010, 43, 6261-6263. DOI: 10.1021/ma101156e

Du, K., Glogowski, E., Emrick, T., Russell, TP., Dinsmore, AD. “Adsorption energy of nano- and microparticles at liquid-liquid interfaces” Langmuir, 2010, 26, 12518-12522. DOI: 10.1021/la100497h

Hu YX., Chen, DA., Park, S., Emrick, T., Russell, TP. “Guided assemblies of ferritin nanocages: Highly ordered arrays of monodisperse nanoscopic elements” Advanced Materials, 2010, 22, 2583-2587. DOI: 10.1002/adma.200903578

Early, KT., Sudeep, PK., Emrick, T., Barnes, MD. “Polarization-driven stark shifts in quantum dot luminescence from single CdSe/oligo-PPV nanoparticles” Nano Letters, 2010, 10, 1754-1758. DOI: 10.1021/nl1001789

Ranganathan, T., Cossette, P., Emrick, T. “Halogen-free, low flammability polyurethanes derived from deoxybenzoin-based monomers” Journal of Materials Chemistry, 2010, 20, 3681-3687. DOI: 10.1039/b924034a

Lee, JU., Jung, JW., Emrick, T., Russell, TP., Jo, WH. “Synthesis of C-60-end capped P3HT and its application for high performance of P3HT/PCBM bulk heterojunction solar cells” Journal of Materials Chemistry, 2010, 20, 3287-3294. DOI: 10.1039/b923752f

Joralemon, MJ., Mcrae, S., Emrick, T. “PEGylated polymers for medicine: From conjugation to self-assembled systems” Chemical Communications, 2010, 46, 1377-1393. DOI: 10.1039/b920570p

Lee, JU., Jung, JW., Emrick, T., Russell, TP., Jo, WH. “Morphology control of a polythiophene-fullerene bulk heterojunction for enhancement of the high-temperature stability of solar cell performance by a new donor-acceptor diblock copolymer” Nanotechnology, 2010, 21. DOI: 10.1088/0957-4484/21/10/105201

Kolmakov, GV., Revanur, R., Tangirala, R., Emrick, T., Russell, TP., Crosby, AJ., Balazs, AC. “Using nanoparticle-filled microcapsules for site-specific healing of damaged substrates: Creating a "repair-and-go" system” ACS Nano, 2010, 4, 1115-1123. DOI: 10.1021/nn901296y


Niu, ZW., Kabispatpathy, S., He, JB., Lee, LA., Rong, JH., Yang, L., Sikha, G., Popov, BN., Emrick, TS., Russell, TP., Wang, Q. “Synthesis and characterization of bionanoparticle-silica composites and mesoporous silica with large pores” Nano Research, 2009, 2, 474-485. DOI: 10.1007/s12274-009-9043-6

Sudeep, PK., Emrick, T. “Functional Si and CdSe quantum dots: Synthesis, conjugate formation, and photoluminescence” ACS Nano, 2009, 3, 4105-4109. DOI: 10.1021/nn901016u

Chen, XJ., McRae, S., Parelkar, S., Emrick, T. “Polymeric phosphorylcholine-camptothecin conjugates prepared by controlled free radical polymerization and click chemistry” Bioconjugate Chemistry, 2009, 20, 2331-2341. DOI: 10.1021/bc900339x

Cooper, BM., Emrick, T. “Sequential and localized grafting on aliphatic polyester diblock copolymers using alkyne deprotection and click cycladdition” Journal of Polymer Science Part A – Polymer Chemistry, 2009, 47, 7054-7065. DOI: 10.1002/pola.23745

Sudeep, PK., Emrick, T. “Pearls of wisdom: Stringing nanoparticles and polymers into new assemblies and materials” ACS Nano, 2009, 3, 2870-2875. DOI: 10.1021/nn901358a

Du, K., Knutson, CR., Glogowski, E., McCarthy, KD., Shenhar, R., Rotello, VM., Tuominen, MT., Emrick, T., Russell, TP., Dinsmore, AD. “Self-assembled electrical contact to nanoparticles using metallic droplets” Small, 2009, 5, 1974-1977. DOI: 10.1002/smll.200900203

Chan-Seng, D., Ranganathan, T., Zhang, XF., Tang, YW., Lin, Q.; Kleiner, L., Emrick, T. “Aliphatic polyester terpolymers for stent coating and drug elution: Effect of polymer composition on drug solubility and release” Drug Delivery, 2009, 16, 304-311. DOI: 10.1080/10717540902999653

Doi, MY., Early, KT., Tangirala, R., Sudeep, PK., Emrick, T., Barnes, MD. “Probing multiexcitonic emission in single CdSe-Oligo(phenylenevinylene) composite nanostructures” Journal of Physical Chemistry, 2009, 113, 13462-13465. DOI: 10.1021/jp9051787

Kratz, K., Breitenkamp, K., Hule, R., Pochan, D., Emrick, T. "PC-Polyolefins: Synthesis and assembly behavior in water" Macromolecules, 2009, 42, 3227-3229. DOI: 10.1021/ma900653h

He, JB., Niu, ZW., Tangirala, R., Wan, JY., Wei, XY., Kaur, G., Wang, Q., Jutz, G., Boeker, A., Lee, B., Pingali, SV., Thiyagaran, P., Emrick, T., Russell, TP. "Self-assembly of tobacco mosaic virus at oil/water interfaces" Langmuir, 2009, 25, 4979-4987. DOI: 10.1021/la803533n

Kaur, G., He, JB., Xu, J., Pingali, SV., Jutz, G., Boker, A., Niu, ZW., Li, T., Rawlinson, D., Emrick, T., Lee, B., Thiyagarajan, P., Russell, TP., Wang, Q. "Interfacial assembly of turnip yellow mosaic virus nanoparticles" Langmuir, 2009, 25, 5168-5176. DOI: 10.1021/la900167s

Tangirala, R., Hu YX., Joralemon, M., Zhang, QL., He, JB., Russell, TP., Emrick, T. "Connecting quantum dots and bionanoparticles in hybrid nanoscale ultra-thin films" Soft Matter, 2009, 5, 1048-1054. DOI: 10.1039/b807757f

Chen, D., Chen, JT., Glogowski, E., Emrick, T., Russell, TP. "Thin film instabilities in blends under cylindrical confinement" Macromolecular Rapid Communications, 2009, 30, 377-383. DOI: 10.1002/marc.200800730

Lee, JU., Cirpan, A., Emrick, T., Russell, TP., Jo, WH. "Synthesis and photophysical property of well-defined donor-acceptor diblock copolymers based on regioregular poly(3-hexythiophene) and fullerene" Journal of Materials Chemistry, 2009, 19, 1483-1489. DOI: 10.1039/b813368a

Early, KT., McCarthy, KD., Odoi MY., Sudeep, PK., Emrick, T., Barnes, MD. "Linear dipole behavior in single CdSe-Oligo(phenylene vinylene) nanostructures" ACS Nano, 2009, 3, 453-461. DOI: 10.1021/nn800785s

Zhang, QL., Cirpan, A., Russell, TP., Emrick, T. "Donor-acceptor poly(thiophene-block-perylene diimide) copolymers: Synthesis and solar cell fabrication" Macromolecules, 2009, 42, 1079-1082. DOI: 10.1021/ma801504e

Ryu, BY., Moon, S., Kosif, I., Ranganathan, T., Farris, RJ., Emrick, T.  "Deoxybenzoin-based epoxy resins" Polymer, 2009, 50, 767-774. DOI: 10.1016/j.polymer.2008.12.009

Cooper, BM., Chan-Seng, D., Samanta, D., Zhang, XF., Parelkar, S., Emrick, T.  “Polyester-graft-phosphorylcholine prepared by ring-opening polymerization and click chemistry” Chem. Commun. 2009, 7, 815-817. DOI: 10.1039/b817600k

Moon, S., Ku, B.C., Emrick, T., Coughlin, BE., Farris, RJ. “Flame resistant electrospun polymer nanofibers from deoxybenzoin” Journal of Applied Polymer Science, 2009, 111, 301-307. DOI: 10.1002/app.29067


Sudeep, PK., Page, Z., Emrick, T. “PEGylated silicon nanoparticles: Synthesis and characterization” Chemical Communications, 2008, 46, 6126-6127. DOI: 10.1039/b813025f

Li, T., Niu, Z., Emrick, T., Russell TR., Wang, Q.  “Core/Shell biocomposites from the hierarchical assembly of bionanoparticles and polymer” Small, 2008, 4, 1624-1629. DOI: 10.1002/smll.200800403

Samanta, D., McRae, S., Cooper, B., Hu, Y., Emrick, T.  “End-functionalized phosphorylcholine methacrylates and their use in protein conjugation” Biomacromolecules, 2008, 9, 2891-2897. DOI: 10.1021/bm8006715  

Breitenkamp, RB., Emrick, T.  “Pentalysine-grafted ROMP polymers for DNA complexation and delivery” Biomacromolecules, 2008, 9, 2495-2500. DOI: 10.1021/bm800511p

Mark, P.R.; Murthy, N.S.; Weigand, S.; Breitenkamp, K.; Kade, M.; Emrick, T.  “Microphase separated structures in the solid and molten states of double-crystal graft copolymers of polyethylene and poly(ethylene oxide)” Polymer, 2008, 49, 3116-3124. DOI: 10.1016/j.polymer.2008.05.012

Lyon, R.E.; Emrick, T.  “Non-halogen fire resistant plastics for aircraft interiors” Polymers for Advanced Technologies, 2008, 19, 609-619. DOI: 10.1002/pat.1126

Ranganathan, T.; Beaulieu, M.; Ziberman, J.; Smith, K.D.; Westmoreland, P.R.; Farris, R.J.; Coughlin, E.B.; Emrick, T.  “Thermal degradation of deoxybenzoin polymers studied by pyrolysis-gas chromatography/mass spectrometry” Polymer Degradation and Stability, 2008, 93, 1059-1066. DOI: 10.1016/j.polymdegradstab.2008.03.021

Li, Q.F; He, J.B.; Glogowski, E.; Li, X.F.; Wang, J.; Emrick, T.; Russell, T.P.  “Responsive assemblies: Gold nanoparticles with mixed ligands in microphase separated block copolymers” Advanced Materials 2008, 20, 1462-1466. DOI: 10.1002/adma.200702004

Rathnayake, H.P.; Emrick, T.  “Grafting-from nanoparticles using aldol group transfer polymerization” Macromolecules 2008, 41, 2969-2971. DOI: 10.1021/ma800571c

Bae, J.; Glogowski, E.; Gupta, S.; Chen, W.; Emrick, T.; Russell, T.P.  “Effect of nanoparticles on the electrohydrodynamic instabilities of polymer/nanoparticle thin films” Macromolecules 2008, 41, 2722-2726. DOI: 10.1021/ma702750y

Bruckman, M.A.; Kaur, G.; Lee, L.A.; Xie, F.; Sepulvecla, J.; Breitenkamp, R.; Zhang, X.; Joralemon, M.; Russell, T.P; Emrick, T.; Wang, Q. “Surface modification of tobacco mosaic virus with “Click” chemistry” Chembiochem 2008, 9, 519-523. DOI: 10.1002/cbic.200700559

Sudeep, P.K.; Early, K.T.; McCarthy, K.D.; Odoi, M.Y.; Barnes, M.D.; Emrick, T.  “Monodisperse oligo(phenylene vinylene) ligands on CdSe quantum dots:  Synthesis and polarization anisotropy measurements” J. Am. Chem. Soc. 2008, 130, 2384-2385. DOI: 10.1021/ja077409

Samanta, D.; Kratz, K.; Zhang, X.; Emrick, T.  “A synthesis of PEG- and phosphorylcholine-substituted pyridines to afford water-soluble ruthenium benzylidene metathesis catalysts” Macromolecules 2008, 41, 530-532. DOI: 0.1021/ma7019732


Hammer, N.I.; Emrick, T.; Barnes, M.D.  “Quantum dots coordinated with conjugated organic ligands: new nanomaterials with novel photophysics” Nanoscale Research Letters 2007, 2, 282-290. DOI: 10.1007/s11671-007-9062-8

Odoi, M.Y.; Hammer, N.I.; Early, K.T.; McCarthy, K.D.; Tangirala, R.; Emrick, T.; Barnes, MD. “Fluorescence lifetimes and correlated photon statistics from single CdSe/oligo(phenylene vinylene) composite nanostructures” NanoLetters 2007, 7, 2769-2773. DOI: 10.1021/nl0713068

Early, KT.; McCarthy, KD.; Hammer, NI.; Odoi, MY.; Tangirala, R.; Emrick, T.; Barnes, MD. “Blinking suppression and intensity recurrences in single CdSe-oligo(phenylene vinylene) nanostructures: experiment and kinetic model” Nanotechnology 2007, 18. DOI: 10.1088/0957-4484/18/42/424027

Breitenkamp, R.B.; Ou, Z.; Breitenkamp, K.; Muthukumar, M.; Emrick, T. “Synthesis and Characterization of polyolefin-graft-oligopeptide polyelectrolytes” Macromolecules 2007, 40, 7617-7624. DOI: 10.1021/ma070714v

Boker, A.; He, J.; Emrick, T.; Russell, TP. “Self-assembly of nanoparticles at interfaces” Soft Matter 2007, 3, 1231-1248. DOI: 10.1039/b706609k

Kutuzov, S.; He, J.; Tangirala, R.; Emrick, T.; Russell, TP.; Boker, A. “On the kinetics of nanoparticle self-assembly at liquid/liquid interfaces“ Physical Chemistry Chemical Physics 2007, 9, 6351-6358. DOI: 10.1039/b710060b

Ranganathan, T.; Ku, B.C.; Zilberman, J.; Beaulieu, M.; Farris, R.J.; Coughlin, E.B.; Emrick, T. “Poly(arylate-phosphonate) copolymers with deoxybenzoin in the backbone: synthesis, characterization, and thermal properties” J. Polym. Sci. A.: Polym. Chem. 2007, 45, 4573-4580. DOI: 10.1002/pola.22188

Sudeep, PK; Emrick, T. “Polymer-nanoparticle composites: Preparative methods and electronically active materials” Polymer Reviews 2007, 47, 155-163. DOI: 10.1080/15583720701271229

Huang, J; Juskiewicz, M; de Jeu, WH; Cerda, E; Emrick, T; Menon, N; Russell, TP. “Capillary wrinkling of floating thin polymer films” Science 2007, 317, 650-653. DOI: 10.1126/science.1144616

He, J; Zhang, Q; Gupta, S; Emrick, T; Russell, TR; Thiyagarajan, P. “Drying Droplets: A window into the behavior of nanorods at interfaces” Small, 2007, 3, 1214-1217. DOI: 10.1002/smll.200700055

Lee, JY; Zhang, Q.; Wang, JY; Emrick T; Crosby, A.J. “Failure mechanism of glassy polymer-nanoparticle composites” Macromolecules, 2007, 40, 6406-6412. DOI: 10.1021/ma0710479

Zhang, Q.; Russell, T.P.; Emrick, T. “Synthesis and Characterization of CdSe Nanorods Functionalized with Regioregular Poly(3-hexylthiophene)’ Chem. Mater., 2007, 19, 3712-3716. DOI: 10.1021/cm070603a

Revanur, R.; McCloskey, B.; Breitenkamp, K.; Freeman, B.D.; Emrick, T. “Reactive amphiphilic graft copolymer coatings applied to poly(vinylidene fluoride) ultrafiltration membranes,” Macromolecules,  2007, 40, 3624-3630.  DOI: 10.1021/ma0701033

Glogowski, E.; Tangirala, R.; He, J.B.; Russell, T.P.; Emrick, T. “Microcapsules of PEGylated gold nanoparticles prepared by fluid-fluid interfacial assembly,”  NanoLetters,  2007, 7, 389-393. DOI: 10.1021/nl062581h

He, J.B.; Tangirala, R.; Emrick, T.; Russell, T.P.  “Self-assembly of nanoparticle-copolymer mixtures: A kinetic point of view,” Advanced Materials, 2007 19, 381-386. DOI: 10.1002/adma.200602094

Zou, S.; Hong, R.; Emrick, T.; Walker, G.  “Ordered CdSe nanoparticles within self-assembled block copolymer domains on surfaces,”  Langmuir, 2007, 23, 1612-1614. DOI: 10.1021/la0629274

Tangirala R.; Revanur R.; Russell T.P.; Emrick T. “Sizing nanoparticle-covered droplets by extrusion through track-etch membranes,” Langmuir, 2007, 23, 965-969. DOI: 10.1021/la061575y

Parrish B.; Emrick T. “Soluble camptothecin derivatives prepared by click cycloaddition chemistry on functional aliphatic polyesters,” Bioconjugate Chemistry, 2007, 18, 263-267. DOI: 10.1021/bc060201d

Hammer, NI., Emrick, T., Barnes, MD. “Quantum dots coordinated with conjugated organic ligands: new nanomaterials with novel photophysics” Nanoscale Research Letters, 2007, 2, 282-290. DOI: 10.1007/s11671-007-9062-8


Hong, R; Fernandez, J.M; Nakade, H; Emrick, T; “In situ observation of place exchange reactions of gold nanoparticles:  Correlation of monolayer structure and stability”, Chemical Communications, 2006, 22: 2347-2349. DOI: 10.1039/b603988j

Balazs, A.C.; Emrick, T.; Russell, T.P. “Nanoparticle-polymer Composites:  Where Two Small Worlds Meet” Science, 2006, 314, 1107-1110. DOI: 10.1126/science.1130557

Zhang, Q.L.; Gupta, S.; Emrick, T.; Russell, T.P.  “Surface-functionalized CdSe nanorods for assembly in diblock copolymer templates,” J. Am. Chem. Soc. 2006, 128, 3898-3899. DOI: 10.1021/ja058615p

Gupta, S; Zhang, Q.L.; Emrick, T.; Russell, T.P.  “Self-corralling" nanorods under an applied electric field” NanoLetters 2006, 6, 2066-2069. DOI: 10.1021/nl061336v

Ranganathan T., Zilberman J., Farris R.J., Coughlin E.B., Emrick T. “Synthesis and characterization of halogen-free antiflammable polyphosphonates containing 4,4'-bishydroxydeoxybenzoin”, Macromolecules 2006, 39, 5974-5975. DOI: 10.1021/ma0614693

Jordan B.J., Hong R., Gider B., Hill J., Emrick T., Rotello, V.M. “Stabilization of alpha-chymotrypsin at air-water interface through surface binding to gold nanoparticle scaffolds” Soft Matter 2 (7): 558-560 2006 DOI: 10.1039/b603980d

Glogowski E., Tangirala R., Russell T.P., Emrick T. “Functionalization of nanoparticles for dispersion in polymers and assembly in fluids” J. Polym. Sci. A: Polym. Chem. 44 (17): 5076-5086 2006 DOI: 10.1002/pola.21598

Hammer N.I., Early K.T., Sill K., Odoi M.Y., Emrick T., Barnes M.D. “Coverage-mediated suppression of blinking in solid state quantum dot conjugated organic composite nanostructures”, J. Phys. Chem. B. 2006, 110, 14167-14171. DOI: 10.1021/jp062065f

Niu Z.W., Bruckman M., Kotakadi V.S., He J.B., Emrick T., Russell T.P., Yang L., Wang Q. “Study and characterization of tobacco mosaic virus head-to-tail assembly assisted by aniline polymerization”, Chem. Commun. 2006, 28, 3019-3021. DOI: 10.1039/b603780a

Lee J.Y., Zhand Q.L., Emrick T., Crosby A.J. “ Nanoparticle alignment and repulsion during failure of glassy polymer nanocomposites” Macromolecules  2006, 39, 7392-7396. DOI: 10.1021/ma061210k

Cardoen G. Breitenkamp K., Emrick T., Coughlin E.B. “Manifold assembly for the convenient polymerization of ethylene oxide and butadiene” Macromolecules 2006, 39, 7170-7173. DOI: 10.1021/ma061379y

Ellzey, K.A., Ranganathan, T., Zilberman, J., Coughlin, EB; Farris, R.J., Emrick, T. “Deoxybenzoin-based Polyarylates as Halogen-free Fire-resistant Polymers”, Macromolecules 2006, 39, 3553-3558. DOI: 10.1021/ma052777o

Gupta, S.; Zhang, QL.; Emrick, T.; Balazs, A.C.; Russell, T.P. “Entropy-driven Segregation of Nanoparticles to Cracks: A Route to Self-healing Systems,” Nature Materials 2006, 5, 229-233. DOI: 10.1038/nmat1582

Odoi, M.Y.; Hammer, N.I.; Sill, K.; Emrick, T.; Barnes, M.D. “Observation of enhanced energy transfer in individual quantum dot-oligophenylene vinylene nanostructures” J. Am. Chem. Soc. 2006, 128, 3506-3507. DOI: 10.1021/ja058429j


Glogowski, E.; He, J.B.; Russell, T.P.; Emrick, T. “Mixed monolayer coverage on gold nanoparticles for interfacial stabilization of immiscible fluids,” Chem. Commun. 2005, 32, 4050-4052. DOI: 10.1039/b503670d

Parrish, B.; Breitenkamp, R.B.; Emrick, T.  “PEG and Peptide-grafted Aliphatic Polyesters by Click Chemistry”  J. Am. Chem. Soc., 2005, 127, 7404-7410. DOI: 10.1021/ja050310n

Skaff, H.; Lin, Y.; Tangirala, R.; Breitenkamp, K.; Boker, A.; Russell, T.P.; Emrick, T. “Cross-linked Capsules of Quantum Dots by Interfacial Assembly and Ligand Cross-linking” Adv. Mater. 2005, 17, 2082-2085.  DOI: 10.1002/adma.200500587

Sill, K.; Emrick, T. “Bis-dendritic Polyethylene Prepared by Ring-opening Metathesis Polymerization in the Presence of Bis-dendritic Chain Transfer Agents”, J. Polym. Sci. A.: Polym. Chem. 2005, 43, 5429-5439. DOI: 10.1002/pola.20995

Breitenkamp, K.; Emrick, T.  “Amphiphilic Ruthenium Benzylidene Metathesis Catalysts with PEG-substituted Pyridine Ligands,” J. Polym. Sci. A.: Polym. Chem. 2005, 43, 5715-5721. DOI: 10.1002/pola.21061

Russell, J.T.; Lin, Y.; Boker, A.; Su, L; Carl, P.; Zettl, H.; He, J.B.; Sill, K.; Tangirala, R.; Emrick, T.; Littrell, K.; Thiyagarajan, P.; Cookson, D.; Fery, A.; Wang, Q.; Russell, T.P.  “Self-assembly and Cross-linking of Bionanoparticles at Liquid-Liquid Interfaces,”  Angew. Chem. Int. Ed. 2005, 44, 2420-2426. DOI: 10.1002/anie.200462653

Lin, Y.; Boker, A.; He, J.B.; Sill, K.; Xiang, H.Q.; Abetz, C.; Li, X.F.; Wang, J.; Emrick, T.; Long, S.; Wang, Q.; Balas, A.; Russell, T.P.  “Self-directed Self-assembly of Nanoparticle/copolymer Mixtures”  Nature 2005, 434, 55-59. DOI: 10.1038/nature03310

Zhang, Q.; Xu, T.; Butterfield, D.; Misner, M.J.; Ryu, D.Y.; Emrick, T.; Russell, T.P. “Controlled Placement of CdSe Nanoparticles in Diblock Copolymer Templates by Electrophoretic Deposition” NanoLetters 2005, 5, 357-361. DOI: 10.1021/nl048103t

Ki, C.D.; Emrick, T.; Chang, J.Y. “Preparation of Functional Nanoporous Silica for Encapsulation of CdSe Nanoparticles”, Adv. Mater. 2005, 17, 230-233. DOI: 10.1002/adma.200400184

Lin, Y.; Boeker, A.; Skaff, H.; Cookson, D.; Dinsmore, A.D.; Emrick, T.; Russell, T.P. “Nanoparticle Assembly at Fluid Interfaces: Structure and Dynamics”  Langmuir, 2005, 21, 191-194. DOI: 10.1021/la048000q

Hong, R.; Fischer, N.O.; Emrick, T.; Rotello, V.M. “Surface PEGylation and Ligand Exchange Chemistry of FePt Nanoparticles for Biological Applications” Chem. Mater. 2005, 17, 4617-4621. DOI: 10.1021/cm0507819


Skaff, H.; Emrick, T.  “Reversible Addition-Fragmentation Chain Transfer Polymerization from the Surface of Unprotected CdSe Nanoparticles” Angew. Chem. Int. Ed.  2004, 43, 5383-5386. DOI: 10.1002/anie.200453822

Skaff, H.; Sill, K.; Emrick, T. “Quantum Dots Tailored with Poly(para-phenylene vinylene)” J. Am. Chem. Soc. 2004, 126, 11322-11325.  DOI: 10.1021/ja047260r

Parrish, B.; Emrick, T. “Aliphatic Polyesters with Pendant Cyclopentene Groups: Controlled Synthesis and Conversion to Polyester-graft-PEG Copolymers” Macromolecules 2004, 37, 5863-5865. DOI: 10.1021/ma048981d

Boeker, A.; Lin, T.; Chiapperini, K.; Horowitz, R.; Thompson, M.; Carreon, V.; Xu, T.; Abetz, C.; Skaff, H.; Dinsmore, A.D.; Emrick, T.; Russell, T.P. “Hierarchical Nanoparticle Assemblies Formed by Decorating Breath Figures” Nature Materials  2004, 3, 302-306.  DOI: 10.1038/nmat1110

Sill, K.; Emrick, T. “Nitroxide-Mediated Radical Polymerization from CdSe Nanoparticles”, Chemistry of Materials, 2004, 16, 1240-1243.  DOI: 10.1021/cm035077b

Hong, R.; Fisher, N.O.; Verma, A.; Goodman, C.M.; Emrick, T.; Rotello, V.M. “Control of Protein Structure and Function through Surface Recognition by Tailored Nanoparticle Scaffolds” J. Am. Chem. Soc. 2004, 126, 739-743. DOI: 10.1021/ja037470o

Hong, R.; Emrick, T.; Rotello, V.M. “Monolayer-controlled Substrate Selectivity using Non-covalent Enzyme-Nanoparticle Conjugates”  J. Am. Chem. Soc. 2004, 126, 13572-13573.  DOI: 10.1021/ja0461163


Breitenkamp, K.; Emrick, T.  “Novel Polymer Capsules from Amphiphilic Graft Copolymers and Ring-opening Cross Metathesis”  J. Am. Chem. Soc. 2003, 125, 12070-12071.  DOI: 10.1021/ja036561i

Lin Y.; Skaff, H.; Boker, A.; Dinsmore, A.D.; Emrick, T.; Russell, T.P.  “Ultrathin Cross-linked Nanoparticle Membranes”  J. Am. Chem. Soc.  2003, 125, 12690-12691.  DOI: 10.1021/ja036919a

Lin, Y.; Skaff, H.; Emrick, T.; Dinsmore, A.D.; Russell, T.P. “Nanoparticle assembly and transport at liquid-liquid interfaces”  Science  2003, 299, 226-229.  DOI: 10.1126/science.1078616

Misner, M.J.; Skaff, H.; Emrick, T.; Russell, T.P. "Directed Deposition of Nanoparticles using Diblock Copolymer Templates" Advanced Materials, 2003, 15, 221-224. DOI: 10.1002/adma.200390050

Skaff, H.; Emrick, T. "The Use of 4-Substituted Pyridines to Afford Amphiphilic, PEGylated Cadmium Selenide Nanoparticles" Chem. Comm. 2003, 52-53. DOI: 10.1039/b208718a

Ellzey, K.A.; Farris, R.J.; Emrick, T. “Synthetic and Thermal Studies of Bisphenol-C Containing Poly(aryletherketone)” Polym. Bull. 2003, 50, 235-242.

Evans, RN., Gilardi, R., Emrick, T. “1-(p-biphenyl)-4 '-(2-naphthyl)cubane” Acta Crystallographica Section E-Structure Reports Online, 2003, 59, O1283-O1285. DOI: 10.1107/S160053803017483


Breitenkamp, K.; Simeone, J.; Jin, E.; Emrick, T. "Novel Amphiphilic Graft Copolymers Prepared by Ring-opening Metathesis Polymerization of Poly(ethylene glycol)-Substituted Cyclooctene Macromonomers”  Macromolecules  2002, 35, 9249-9252. 

Parrish, B.; Quansah, J.K.; Emrick, T. "Functional Polyesters Prepared by Polymerization of a-Allyl(d-valerolactone), and its Copolymerization with e-Caprolactone and d-Valerolactone" J. Polym. Sci. Part A: Polym. Chem.  2002, 40, 1983-1990.

Skaff, H.; Ilker, M.F.; Coughlin, E.B.; Emrick, T.  “Preparation of Cadmium Selenide-Polyolefin Composites from Functional Phosphine Oxides and Ruthenium-based Metathesis” J. Am. Chem. Soc. 2002, 124, 5729-5733.


Emrick, T.; Chang, H-T.; Fréchet, J.M.J.  "The Preparation of Hyperbranched Aromatic and Aliphatic Polyether Epoxies by Chloride-Catalyzed Proton Transfer Polymerization from AB(n) and A(2) + B-3 Monomers"  J. Polym. Sci. Part A: Polym. Chem. 2000, 33, 4850. DOI: 10.1002/1099-0518(200012)38:1+<4850::AID-POLA230>3.0.CO;2-G

Hecht, S.; Emrick, T.; Fréchet, J.M.J.  "Hyperbranched Porphyrins - A Rapid Synthetic Approach To Multiporphyrin Macromolecules"  Chem. Commun. 2000, 313. DOI: 10.1039/a909258g

Emrick, T.; Chang, H.T.; Fréchet, J.M.J., Baccei, L., Woods, J.  "Hyperbranched Aromatic Epoxies in the Design of Adhesive Materials"  Polym. Bull. 2000, 45, 1. DOI: 10.1007/s002890070049


Emrick, T.; Chang, H-T.; Fréchet, J.M.J  "An A(2)+B-3 Approach to Hyperbranched Aliphatic Polyethers Containing Chain End Epoxy Substituents"  Macromolecules 1999, 32, 6380. DOI: 10.1021/ma990687b

Emrick, T.; Hayes, W.; Fréchet, J.M.J.  "A TEMPO Mediated “Living” Free Radical Approach to ABA Triblock Dendritic-Linear Hybrid Copolymers"  J. Polym. Sci. Part A: Polym. Chem. 1999, 37, 3748. DOI: 10.1002/(SICI)1099-0518(19991015)37:20<3748::AID-POLA2>3.3.CO;2-8

Emrick, T; Fréchet, J.M.J.  "Self-Assembly of Dendritic Structures"  Curr. Opin. Coll. In. Sci.  1999, 4, 15-23.  DOI: 10.1016/S1359-0294(99)00008-4

Eaton, P.E.; Pramod, K.; Emrick, T., Gilardi, R.  "Building with Cubane-1,4-diyl.  Synthesis of Aryl Substituted Cubanes, p-[n]Cubyls, and Cubane Separated Bis-Arenes"  J. Am. Chem. Soc. 1999, 121, 4111. DOI: 10.1021/ja983441f  

Yildrim, T., Kilic, C., Ciraci, S., Gehring, PM., Neumann, DA., Eaton, PE., Emrick, T. “Vibrations of the cubane molecule: inelastic neutron scattering study and theory” Chemical Physics Letters, 1999, 309, 234-240. DOI: 10.1016/S0009-2614(99)00655-7

Yildrim, T., Gehring, PM., Neumann, DA., Eaton, PE., Emrick, T. “Neutron-scattering investigation of molecular reorientations in solid cubane” Physical Review B, 1999, 60, 314-321. DOI: 10.1103/PhysRevB.60.314


Yildirim, T.; Gehring, P.M.; Neumann D.A.; Eaton, P.E.; Emrick, T.  "Solid Cubane: A Brief Review" Carbon 1998, 36, 809.  

Yildrim, T., Gehring, PM., Neumann, DA., Eaton, PE., Emrick, T. “Unusual structure, phase transition, and dynamics of solid cubane” Physical Review Letters, 1997, 78, 4938-4941. DOI: 10.1103/PhysRevLett.78.4938  

Hare, M.; Emrick, T.; Eaton, P.E.; Kass, S.R.  "Cubyl Anion Formation and an Experimental Determination of the Acidity and C-H Bond Dissociation Energy of Cubane"  J. Am. Chem. Soc. 1997, 119, 237.  

Engling, G.; Emrick, T.; Hellmann, J.; McElroy, E.; Brandt, M.; Reingold, I.D.  "A Novel Approach to Bicyclo[3.3.0]octane-2,8-dione"  J. Org. Chem. 1994, 59, 1945-1946.