University of Massachusetts Amherst

Polymer Science and Engineering

Emrick Research Group – Publications

Most Cited Publications

137. Lee, DY., Pham, JT., Lawrence, J., Lee, CH., Parkos, C., Emrick, T., Crosby, AJ. “Macroscopic Nanoparticle Ribbons and Fabrics” Advanced Materials, 2013, 9, 1248-1253.

136. Laprade, EJ., Long, R., Pham, JT., Lawrence, J., Emrick, T., Crosby, AJ., Hui, CY., Shull, KR. “Large Deformation and Adhesive Contact Studies of Axisymmetric Membranes” Langmur, 2013, 5, 1407-1419.

135. Page, ZA., Duzhko, VV., Emrick, T. “Conjugated Thiophene-Containing Polymer Zwitterions: Direct Synthesis and Thin Film Electronic Properties” Macromolecules, 2013, 2, 344-351.

134. Chen, XJ., Lawrence, J., Parelkar, S., Emrick, T. “Novel Zwitterionic Copolymers with Dihydrolipoic Acid: Synthesis and Preparation of Nonfouling Nanorods” Macromolecules, 2013, 1, 119-127.

133. Bu, L., Pentzer, E., Bokel, F., Emrick, T., Hayward, R. “Growth of polythiophene/perylene tetracarboxydiimide donor/acceptor shish-kebab nanostructures by coupled crystal modification” ACS Nano, 2012, 6, 10924-10929.

132. Chen, XJ., Parelkar, S., Henchey, E., Schneider, S., Emrick, T. “PolyMPC-Doxorubicin Prodrugs” Bioconjugate Chemistry, 2012, 23, 1753-1763.

131. Silvers, A., Chang, CC., Emrick, T. “Functional aliphatic polyesters and nanoparticles prepared by organocatalysis and orthogonal grafting chemistry” Journal of Polymer Science Part A – Polymer Chemistry, 2012, 50, 3517-3529.

130. Mcrae, S; Chen, XJ.; Kratz, K.; Samanta, D.; Henchey, E.; Schneider, S.; Emrick, T. “Pentafluorophenyl Ester-Functionalized Phosphorylcholine Polymers: Preparation of Linear, Two-Arm, and Grafted Polymer-Protein Conjugates” Biomacromolecules, 2012, 13, 2099-2109.

129. Baghgar, M.; Labastide, J.; Bokel, F.; Dujovne, I.; McKenna, A.; Barnes, AM.; Pentzer, E.; Emrick, T.; Hayward, R.; Barnes, MD. “Probing Inter- and Intrachain Exciton Coupling in Isolated Poly(3-hexylthiophene) Nanofibers: Effect of Solvation and Regioregularity” Journal of Physical Chemistry Letters, 2012, 3, 1674-1679.

128. Bae, J.; Lawrence, J.; Miesch, C.; Ribbe, A.; Li, W.; Emrick, T.; Zhu, J.; Hayward, RC. “Multifunctional Nanoparticle-Loaded Spherical and Wormlike Micelles Formed by Interfacial Instabilities” Advanced Materials, 2012, 24, 2735-2741.

127. Pentzer, EB.; Bokel, FA.; Hayward, RC.; Emrick, T. “Nanocomposite “Superhighways” by Solution Assembly of Semiconductor Nanostructures with Ligand-Functionalized Conjugated Polymers” Advanced Materials, 2012, 24, 2254-2258.

126. Kratz, K.; Narasimhan, A.; Tangirala, R.; Moon, SC.; Revanu, R.; Kundu, S.; Kim, HS.; Crosby, AJ.; Russell, TP.; Emrick, T.; Kolmakov, G.; Balazs, AC. “Probing and repairing damaged surfaces with nanoparticle-containing microcapsules” Nature Nanotechnology, 2012, 7, 87-90.

125. Ravichandran, S.; Nagarajan, S.; Ku, BC.; Coughlin, B.; Emrick, T.; Kumar, J.; Nagarajan, R. “Halogen-free ultra-high flame retardant polymers through enzyme catalysis” Green Chemistry, 2012, 14, 819-824.

124. Miesch, C.; Kosif, I.; Lee, E.; Kim, JK.; Russell, TP.; Hayward, RC.; Emrick, T. “Nanoparticle-Stabilized Double Emulsions and Compressed Droplets” Angewandte Chemie-International Edition, 2012, 51, 145-149.


123. Kratz, K.; Xie, W.; Lee, A.; Freeman, BD.; Emrick, T. “Phosphorylcholine-Substituted ROMP Polyolefin Coatings Provide Fouling Resistance to Membrane Materials” Macromolecular Materials and Engineering, 2011, 296, 1142-1148.

122. Elder, RM.; Emrick, T.; Jayaraman, A. “Understanding the Effect of Polylysine Architecture on DNA Binding Using Molecular Dynamics Simulations” Biomacromolecules, 2011, 12, 3870-3879.

121. Hammer, BAG.; Bokel, FA.; Hayward, RC.; Emrick, T. “Cross-Linked Conjugated Polymer Fibrils: Robust Nanowires from Functional Polythiophene Diblock Copolymers” Chemistry of Materials, 2011, 23, 4250-4256.

120.Ryu, BY.; Emrick, T. “Bisphenol-1,2,3-triazole (BPT) Epoxies and Cyanate Esters: Synthesis and Self-Catalyzed Curing” Macromolecules, 2011, 44, 5693-5700.

119.Lee, E.; Hammer, B.; Kim, JK.; Page, Z.; Emrick, T.; Hayward, RC. “Hierarchical Helical Assembly of Conjugated Poly(3-hexylthiophene)-block-poly(3-triethylene glycol thiophene) Diblock Copolymers” Journal of the American Chemical Society, 2011, 133, 10390-10393.

118. Su, GM.; Best, K.; Ranganathan, T.; Emrick, T.; Crosby, AJ. “Tailored Nanoparticles for Enhancing Polymer Adhesion” Macromolecules, 2011, 44, 5256-5261.

117.Li, L.; Miesch, C.; Sudeep, PK.; Balazs, AC.; Emrick, T.; Russell, TP.; Hayward, RC. “Kinetically Trapped Co-continuous Polymer Morphologies through Intraphase Gelation of Nanoparticles” Nano Letters, 2011, 11, 1997-2003.

116. Bokel, FA.; Sudeep, PK.; Pentzer, E.; Emrick, T.; Hayward, RC. “Assembly of Poly(3-hexylthiophene)/CdSe Hybrid Nanowires by Cocrystallization” Macromolecules, 2011, 44, 1768-1770.

115. Parelkar, SS.; Chan-Seng, D.; Emrick, T. “Reconfiguring polylysine architectures for controlling polyplex binding and non-viral transfection” Biomaterials, 2011, 32, 2432-2444.


114. Pochan, D., Zhu, J., Zhang, K., Wooley, K., Miesch, C., Emrick, T. “Multicompartment and Multigeometry Nanoparticle Assembly” Soft Matter, 2010, 7, 2500-2506.

113. Kim, H.S., Lee, C.H., Sudeep, PK., Emrick, T.; Crosby, A. “Nanoparticle Stripes, Grids, and Ribbons Produced by Flow Coating” Advanced Materials, 2010, 22, 4600-4604.

112. Hu, Y., Samanta, D., Parelkar, S., Hong, SW., Wang, Q.; Russell, T., Emrick, T. “Ferritin-Polymer Conjugates: Grafting Chemistry and Integration into Nanoscale Assemblies.” Advanced Function Materials, 2010, 20, 3603-3612.

111. Ryu, BY.; Emrick, T. “Thermally Induced Structural Transformation of Bisphenol-1,2,3-triazole Polymers: Smart, Self-Extinguishing Materials” Angewandte Chemie-International Edition, 2010, 49, 9644-9647.

110. Chen, XJ.; McRae, S.; Samanta, D.; Emrick, T. “Polymer-Protein Conjugation in Ionic Liquids” Macromolecules, 2010, 43, 6261-6263.

109. Du, K.; Glogowski, E.; Emrick, T.; Russell, TP. “ Adsorption Energy of Nano- and Microparticles at Liquid-Liquid Interfaces” Langmuir, 2010, 26, 12518-12522.

108. Hu, YX.; Chen, DA.; Park, S.; Emrick, T.; Russell, TP. “ Guided Assemblies of Ferritin Nanocages: Highly Ordered Arrays of Monodisperse Nanoscopic Elements” Advanced Materials, 2010, 22, 2583-2587.

107. Early, KT.; Sudeep, PK.; Emrick, T.; Barnes, MD. “Polarization-Driven Stark Shifts in Quantum Dot Luminescence from Single CdSe/oligo-PPV Nanoparticles” Nano Letters, 2010, 10, 1754-1758.

106. Ranganathan, T.; Cossette, P.; Emrick, T. “ Halogen-free, low flammability polyurethanes derived from deoxybenzoin-based monomers” Journal or Materials Chemistry, 2010, 20, 3681-3687.

105. Lee, JU.; Jung, JW.; Emrick, T.; Russell, TP.; Jo, WH. “ Synthesis of C-60-end capped P3HT and its application for high performance of P3HT/PCBM bulk heterojunction solar cells” Journal of Materials Chemistry, 2010, 20, 3287-3294.

104. Joralemon, MJ.; Mcrae, S.; Emrick, T. “ PEGylated polymers for medicine: from conjugation to self-assembled systems” Chemical Communications, 2010, 46, 1377-1393.

103. Lee, JU.; Jung, JW.; Emrick, T.; Russell, TP.; Jo, WH. “ Morphology control of a polythiophene-fullerene bulk heterojunction for enhancement of the high-temperature stability of solar cell performance by a new donor-acceptor diblock copolymer” Nanotechnology, 2010, 21.

102. Kolmakov, GV.; Revanur, R.; Tangirala, R.; Emrick, T.; Russell, TP.; Crosby, AJ.; Balazs, AC. “Using Nanoparticle-Filled Microcapsules for Site-Specific Healing of Damaged Substrates: Creating a “Repair- and- Go” System” ACS Nano, 2010, 4, 1115-1123.


101. Niu, ZW.; Kabispatpathy, S.; He, JB.; Lee, LA.; Rong, JH.; Yang, L; Sikha, G.; Popov, BN.; Emrick, TS.; Russell, TP.; Wang, Q. “Synthesis and Characterization of Bionanoparticle-Silica Composites and Mesoporous Silica with Large Pores” Nano Research, 2009, 2, 474-485

100. Sudeep, PK.; Emrick, T. “Functional Si and CdSe Quantum Dots: Synthesis, Conjugate Formation, and Photoluminescence” ACS Nano, 2009, 3, 4105-4109.

99. Chen, XJ.; McRae, S.; Parelkar, S.; Emrick, T. “Polymeric Phosphorylcholine-Camptothecin Conjugates Prepared by Controlled Free Radical Polymerization and Click Chemistry” Bioconjugate Chemistry, 2009, 20, 2331-2341.

98. Cooper, BM.; Emrick, T. “Sequential and Localized Grafting on Aliphatic Polyester Diblock Copolymers Using Alkyne Deprotection and Click Cycladdition” Journal of Polymer Science Part A – Polymer Chemistry, 2009, 47, 7054-7065.

97. Sudeep, PK.; Emrick, T. “Pearls of Wisdom: Stringing Nanoparticles and Polymers into New Assemblies and Materials” ACS Nano, 2009, 3, 2870-2875.

96. Du, K.; Knutson, CR.; Glogowski, E.; McCarthy, KD.; Shenhar, R.; Rotello, VM.; Tuominen, MT.; Emrick, T.; Russell, TP.; Dinsmore, AD. “Self-Assembled Electrical Contact to Nanoparticles Using Metallic Droplets” Small, 2009, 5, 1974-1977.

95. Chan-Seng, D.; Ranganathan, T.; Zhang, XF.; Tang, YW.; Lin, Q.; Kleiner, L.; Emrick, T. “Aliphatic polyester terpolymers for stent coating and drug elution: Effect of polymer composition on drug solubility and release” Drug Delivery, 2009, 16, 304-311.

94. Doi, MY.; Early, KT.; Tangirala, R.; Sudeep, PK.; Emrick, T.; Barnes, MD. “Probing Multiexcitonic Emission in Single CdSe-Oligo(phenylenevinylene) Composite Nanostructures” Journal of Physical Chemistry, 2009, 113, 13462-13465.

93. Kratz, K.; Breitenkamp, K.; Hule, R.; Pochan, D.; Emrick, T. "PC-Polyolefins: Synthesis and Assembly Behavior in Water" Macromolecules, 2009, 42, 3227-3229.

92. He, J.B.; Niu, Z.W.; Tangirala, R.; Wan, J.Y.; Wei, X.Y.; Kaur, G.; Wang, Q.; Jutz, G.; Boeker, A.; Lee, B.; Pingali, S.V.; Thiyagaran, P.; Emrick, T.; Russell, T.P. "Self-Assembly of Tobacco Mosaic Virus at Oil/Water Interfaces" Langmuir, 2009, 25, 4979-4987.

91. Kaur, G.; He, J.B.; Xu, J.; Pingali, S.V.; Jutz, G.; Boker, A.; Niu, Z.W.; Li, T.; Rawlinson, D.; Emrick, T.; Lee, B.; Thiyagarajan, P.; Russell, T.P.; Wang, Q. "Interfacial Assembly of Turnip Yellow Mosaic Virus Nanoparticles" Langmuir, 2009, 25, 5168-5176.

90. Tangirala, R.; Hu Y.X.; Joralemon, M.; Zhang, Q.L.; He, J.B.; Russell, T.P.; Emrick, T. "Connecting quantum dots and bionanoparticles in hybrid nanoscale ultra-thin films" Soft Matter, 2009, 5, 1048-1054.

89. Chen, D.; Chen, J.T.; Glogowski, E.; Emrick, T.; Russell, T.P. "Thin Film Instabilities in Blends under Cylindrical Confinement" Macromolecular Rapid Communications, 2009, 30, 377-383.

88. Lee, J.U.; Cirpan, A.; Emrick, T.; Russell, T.P.; Jo, W.H. "Synthesis and photophysical property of well-defined donor-acceptor diblock copolymers based on regioregular poly(3-hexythiophene) and fullerene" Journal of Materials Chemistry, 2009, 19, 1483-1489.

87. Early, K.T.; McCarthy, K.D.; Odoi M.Y.; Sudeep, P.K.; Emrick, T.; Barnes, M.D. "Linear Dipole Behavior in Single CdSe-Oligo(phenylene vinylene) Nanostructures" ACS Nano, 2009, 3, 453-461.

86. Zhang, Q.L.; Cirpan, A.; Russell, T.P.; Emrick, T. "Donor-Acceptor Poly(thiophene-block-perylene diimide) Copolymers: Synthesis and Solar Cell Fabrication" Macromolecules, 2009, 42, 1079-1082.

85. Ryu, B.Y.; Moon, S.; Kosif, I.; Ranganathan, T.; Farris, R.J., Emrick, T.  "Deoxybenzoin-based epoxy resins" Polymer, 2009, 50, 767-774

84. Cooper, B.M.; Chan-Seng, D.; Samanta, D.; Zhang, X.F.; Parelkar, S.; Emrick, T.  “Polyester-graft-phosphorylcholine prepared by ring-opening polymerization and click chemistry” Chem. Commun. 2009, 7, 815-817.

83. Moon, S.; Ku, B.C.; Emrick, T.; Coughlin, B.E., Farris, R.J. “Flame resistant electrospun polymer nanofibers from deoxybenzoin” Journal of Applied Polymer Science, 2009, 111, 301-307.


82. Sudeep, P.K.; Page, Z.; Emrick, T. “PEGylated silicon nanoparticles: synthesis and characterization” Chemical Communications, 2008, 46, 6126-6127.

81.  Li, T.; Niu, Z; Emrick, T.; Russell T.R.; Wang, Q.  “Core/Shell Biocomposites from the Hierarchical Assembly of Bionanoparticles and Polymer” Small, 2008, 4, 1624-1629.

80.  Samanta, D.; McRae, S.; Cooper, B.; Hu, Y.; Emrick, T.  “End-Functionalized Phosphorylcholine Methacrylates and their Use in Protein Conjugation” Biomacromolecules 2008, 9, 2891-2897.

79.  Breitenkamp, R.B.; Emrick, T.  “Pentalysine-grafted ROMP polymers for DNA complexation and delivery” Biomacromolecules, 2008, 9, 2495-2500.

78.  Mark, P.R.; Murthy, N.S.; Weigand, S.; Breitenkamp, K.; Kade, M.; Emrick, T.  “Microphase separated structures in the solid and molten states of double-crystal graft copolymers of polyethylene and poly(ethylene oxide)” Polymer 2008, 49, 3116-3124.

77.  Lyon, R.E.; Emrick, T.  “Non-halogen fire resistant plastics for aircraft interiors” Polymers for Advanced Technologies 2008, 19, 609-619.

76.  Ranganathan, T.; Beaulieu, M.; Ziberman, J.; Smith, K.D.; Westmoreland, P.R.; Farris, R.J.; Coughlin, E.B.; Emrick, T.  “Thermal degradation of deoxybenzoin polymers studied by pyrolysis-gas chromatography/mass spectrometry” Polymer Degradation and Stability 2008, 93, 1059-1066.

75.  Li, Q.F; He, J.B.; Glogowski, E.; Li, X.F.; Wang, J.; Emrick, T.; Russell, T.P.  “Responsive assemblies; Gold nanoparticles with mixed ligands in microphase separated block copolymers” Advanced Materials 2008, 20, 1462-1466.

74.  Rathnayake, H.P.; Emrick, T.  “Grafting-from nanoparticles using aldol group transfer polymerization” Macromolecules 2008, 41, 2969-2971.

73.  Bae, J.; Glogowski, E.; Gupta, S.; Chen, W.; Emrick, T.; Russell, T.P.  “Effect of nanoparticles on the electrohydrodynamic instabilities of polymer/nanoparticle thin films” Macromolecules 2008, 41, 2722-2726.

72.  Bruckman, M.A.; Kaur, G.; Lee, L.A.; Xie, F.; Sepulvecla, J.; Breitenkamp, R.; Zhang, X.; Joralemon, M.; Russell, T.P; Emrick, T.; Wang, Q. “Surface modification of tobacco mosaic virus with “Click” chemistry” Chembiochem 2008, 9, 519-523.

71.  Hammer, N.I.; Emrick, T.; Barnes, M.D.  “Quantum dots coordinated with conjugated organic ligands: new nanomaterials with novel photophysics” Nanoscale Research Letters 2008, 2, 282-290.

70.  Sudeep, P.K.; Early, K.T.; McCarthy, K.D.; Odoi, M.Y.; Barnes, M.D.; Emrick, T.  “Monodisperse oligo(phenylene vinylene) ligands on CdSe quantum dots:  Synthesis and polarization anisotropy measurements” Journal of the American Chemical Society 2008, 130, 2384-2385.

69.  Samanta, D.; Kratz, K.; Zhang, X.; Emrick, T.  “A synthesis of PEG- and phosphorylcholine-substituted pyridines to afford water-soluble ruthenium benzylidene metathesis catalysts” Macromolecules 2008, 41, 530-532.


68. Odoi, M.Y.; Hammer, N.I.; Early, K.T.; McCarthy, K.D.; Tangirala, R.; Emrick, T.; Barnes, MD. “Fluorescence lifetimes and correlated photon statistics from single CdSe/oligo(phenylene vinylene) composite nanostructures” NanoLetters 2007, 7, 2769-2773.

67. Early, KT.; McCarthy, KD.; Hammer, NI.; Odoi, MY.; Tangirala, R.; Emrick, T.; Barnes, MD. “Blinking suppression and intensity recurrences in single CdSe-oligo(phenylene vinylene) nanostructures: experiment and kinetic model” Nanotechnology 2007, 18.   

66. Breitenkamp, RB.; Ou, Z.; Breitenkamp, K.; Muthukumar, M.; Emrick, T. “Synthesis and Characterization of polyolefin-graft-oligopeptide polyelectrolytes” Macromolecules 2007, 40, 7617-7624.

65.  Boker, A.; He, J.; Emrick, T.; Russell, TP. “Self Assembly of nanoparticles at interfaces” Soft Matter 2007, 3, 1231-1248.

64. Kutuzov, S.; He, J.; Tangirala, R.; Emrick, T.; Russell, TP.; Boker, A. “On the kinetics of nanoparticle self-assembly at liquid/liquid interfaces“ Physical Chemistry Chemical Physics 2007, 9, 6351-6358.  

63.  Ranganathan, T.; Ku, B.C.; Zilberman, J.; Beaulieu, M.; Farris, R.J.; Coughlin, E.B.; Emrick, T. “Poly(arylate-phosphonate) copolymers with deoxybenzoin in the backbone: synthesis, characterization, and thermal properties” J. Polym. Sci. A.: Polym. Chem. 2007, 45, 4573-4580.

62. Sudeep, PK; Emrick, T. “Polymer-nanoparticle composites: Preparative methods and electronically active materials” Polymer Reviews 2007, 47, 155-163

61. Huang, J; Juskiewicz, M; de Jeu, WH; Cerda, E; Emrick, T; Menon, N; Russell, TP. “Capillary wrinkling of floating thin polymer films” Science 2007, 317, 650-653.

60. He, J; Zhang, Q; Gupta, S; Emrick, T; Russell, TR; Thiyagarajan, P. “Drying Droplets: A window into the behavior of nanorods at interfaces” Small 2007, 3, 1214-1217.

59. Lee, JY; Zhang, Q.; Wang, JY; Emrick T; Crosby, AJ. “Failure mechanism of glassy polymer-nanoparticle composites” Macromolecules  2007, 40, 6406-6412.

58. Zhang, Q.; Russell, T.P.; Emrick, T. “Synthesis and Characterization of CdSe Nanorods Functionalized with Regioregular Poly(3-hexylthiophene)’ Chem. Mater. 2007, 19, 3712-3716.

57.  Revanur, R.; Mccloskey, B.; Breitenkamp, K.; Freeman, B.D.; Emrick, T. “Reactive amphiphilic graft copolymer coatings applied to poly(vinylidene fluoride) ultrafiltration membranes,” Macromolecules  2007, 40, 3624-3630. 

56. Glogowski, E.; Tangirala, R.; He, J.B.; Russell, T.P.; Emrick, T. “Microcapsules of PEGylated gold nanoparticles prepared by fluid-fluid interfacial assembly,”  NanoLetters  2007, 7, 389-393.

55. He, J.B.; Tangirala, R.; Emrick, T.; Russell, T.P.  “Self-assembly of nanoparticle-copolymer mixtures: A kinetic point of view,” Advanced Materials 2007 19, 381-386.

54. Zou, S.; Hong, R.; Emrick, T.; Walker, G.  “Ordered CdSe nanoparticles within self-assembled block copolymer domains on surfaces,”  Langmuir 2007, 23, 1612-1614.

53. Tangirala R.; Revanur R.; Russell T.P.; Emrick T. “Sizing nanoparticle-covered droplets by extrusion through track-etch membranes,” Langmuir 2007, 23, 965-969.

52. Parrish B.; Emrick T. “Soluble camptothecin derivatives prepared by click cycloaddition chemistry on functional aliphatic polyesters,” Bioconjugate Chemistry  2007, 18, 263-267.


51. Hong, R; Fernandez, J.M; Nakade, H; Emrick, T; “In situ observation of place exchange reactions of gold nanoparticles, Correiation of monolayer structure and stability”, Chemical Communications 2006, 22: 2347-2349 

50.  Balazs, A.C.; Emrick, T.; Russell, T.P. “Nanoparticle-polymer Composites:  Where Two Small Worlds Meet” Science, 2006, 314, 1107-1110.

49.  Zhang, Q.L.; Gupta, S.; Emrick, T.; Russell, T.P.  “Surface-functionalized CdSe nanorods for assembly in diblock copolymer templates,” J. Am. Chem. Soc. 2006, 128, 3898-3899

48. Gupta, S; Zhang, Q.L.; Emrick, T.; Russell, T.P.  “Self-corralling" nanorods under an applied electric field” NanoLetters 2006, 6, 2066-2069.

47. Ranganathan T., Zilberman J., Farris R.J., Coughlin E.B., Emrick T. “Synthesis and characterization of halogen-free antiflammable polyphosphonates containing 4,4'-bishydroxydeoxybenzoin”, Macromolecules 2006, 39, 5974-5975

46. Jordan B.J., Hong R., Gider B., Hill J., Emrick T., Rotello V.M., “Stabilization of alpha-chymotrypsin at air-water interface through surface binding to gold nanoparticle scaffolds “,Soft Matter 2 (7): 558-560 2006
45. Glogowski E., Tangirala R., Russell T.P., Emrick T. “Functionalization of nanoparticles for dispersion in polymers and assembly in fluids”, J. of Polymer Sci. Part A-Polymer Chem. 44 (17): 5076-5086 2006

44. Hammer N.I., Early K.T., Sill K., Odoi M.Y., Emrick T., Barnes M.D. “Coverage-mediated suppression of blinking in solid state quantum dot conjugated organic composite nanostructures”, J. Phys. Chem. B. 2006, 110, 14167-14171.

43.  Niu Z.W., Bruckman M., Kotakadi V.S., He J.B., Emrick T., Russell T.P., Yang L., Wang Q. “Study and characterization of tobacco mosaic virus head-to-tail assembly assisted by aniline polymerization”, Chemical Communications(28): 3019-3021 2006

42.  Lee J.Y., Zhand Q.L., Emrick T., Crosby A.J. “ Nanoparticle alignment and repulsion during failure of glassy polymer nanocomposites” Macromolecules  2006, 39, 7392-7396.

41.  Cardoen G. Breitenkamp K., Emrick T., Coughlin E.B. “Manifold assembly for the convenient polymerization of ethylene oxide and butadiene” Macromolecules 2006, 39, 7170-7173

40.Ellzey, K.A., Ranganathan, T., Zilberman, J., Coughlin, EB; Farris, R.J., Emrick, T. “Novel Deoxybenzoin-based Polyarylates as Halogen-free Fire-resistant Polymers”, Macromolecules 2006, 39, 3553-3558.

39. Gupta, S.; Zhang, QL.; Emrick, T.; Balazs, A.C.; Russell, T.P. “Entropy-driven Segregation of Nanoparticles to Cracks: A Route to Self-healing Systems,” Nature Materials 2006, 5, 229-233.

38. Odoi, M.Y.; Hammer, N.I.; Sill, K.; Emrick, T.; Barnes, M.D. “Observation of enhanced energy transfer in individual quantum dot-oligophenylene vinylene nanostructures” J. Am. Chem. Soc. 2006, 128, 3506-3507.


37.  Glogowski, E.; He, J.B.; Russell, T.P.; Emrick, T. “Mixed monolayer coverage on gold nanoparticles for interfacial stabilization of immiscible fluids,” Chem. Commun. 2005, 32, 4050-4052.

36.  Parrish, B.; Breitenkamp, R.B.; Emrick, T.  “PEG and Peptide-grafted Aliphatic Polyesters by Click Chemistry”  J. Am. Chem. Soc., 2005, 127, 7404-7410.   

35. Skaff, H.; Lin, Y.; Tangirala, R.; Breitenkamp, K.; Boker, A.; Russell, T.P.; Emrick, T. “Cross-linked Capsules of Quantum Dots by Interfacial Assembly and Ligand Cross-linking” Adv. Mater. 2005, 17, 2082-2085. 

34. Sill, K.; Emrick, T. “Bis-dendritic Polyethylene Prepared by Ring-opening Metathesis Polymerization in the Presence of Bis-dendritic Chain Transfer Agents”, J. Polym. Sci. A.: Polym. Chem. 2005, 43, 5429-5439. 

33. Breitenkamp, K.; Emrick, T.  “Amphiphilic Ruthenium Benzylidene Metathesis Catalysts with PEG-substituted Pyridine Ligands,” J. Polym. Sci. A.: Polym. Chem. 2005, 43, 5715-5721. 

32.  Russell, J.T.; Lin, Y.; Boker, A.; Su, L; Carl, P.; Zettl, H.; He, J.B.; Sill, K.; Tangirala, R.; Emrick, T.; Littrell, K.; Thiyagarajan, P.; Cookson, D.; Fery, A.; Wang, Q.; Russell, T.P.  “Self-assembly and Cross-linking of Bionanoparticles at Liquid-Liquid Interfaces,”  Angew. Chem. Int. Ed. 2005, 44, 2420-2426. 

31.  Lin, Y.; Boker, A.; He, J.B.; Sill, K.; Xiang, H.Q.; Abetz, C.; Li, X.F.; Wang, J.; Emrick, T.; Long, S.; Wang, Q.; Balas, A.; Russell, T.P.  “Self-directed Self-assembly of Nanoparticle/copolymer Mixtures”  Nature 2005, 434, 55-59. 

30. Zhang, Q.; Xu, T.; Butterfield, D.; Misner, M.J.; Ryu, D.Y.; Emrick, T.; Russell, T.P. “Controlled Placement of CdSe Nanoparticles in Diblock Copolymer Templates by Electrophoretic Deposition” NanoLetters 2005, 5, 357-361. 

29.  Ki, C.D.; Emrick, T.; Chang, J.Y. “Preparation of Functional Nanoporous Silica for Encapsulation of CdSe Nanoparticles”, Adv. Mater. 2005, 17, 230-233. 

28. Lin, Y.; Boeker, A.; Skaff, H.; Cookson, D.; Dinsmore, A.D.; Emrick, T.; Russell, T.P. “Nanoparticle Assembly at Fluid Interfaces: Structure and Dynamics”  Langmuir, 2005, 21, 191-194.      

27. Hong, R.; Fischer, N.O.; Emrick, T.; Rotello, V.M. “Surface PEGylation and Ligand Exchange Chemistry of FePt Nanoparticles for Biological Applications” Chem. Mater. 2005, 17, 4617-4621.


26.  Skaff, H.; Emrick, T.  “Reversible Addition-Fragmentation Chain Transfer Polymerization from the Surface of Unprotected CdSe Nanoparticles”  Angew. Chem. Int. Ed.  2004, 43, 5383-5386. 

25. Skaff, H.; Sill, K.; Emrick, T. “Quantum Dots Tailored with Poly(para-phenylene vinylene)” J. Am. Chem. Soc. 2004, 126, 11322-11325.  

24. Parrish, B.; Emrick, T. “Aliphatic Polyesters with Pendant Cyclopentene Groups: Controlled Synthesis and Conversion to Polyester-graft-PEG Copolymers” Macromolecules 2004, 37, 5863-5865.  

23. Boeker, A.; Lin, T.; Chiapperini, K.; Horowitz, R.; Thompson, M.; Carreon, V.; Xu, T.; Abetz, C.; Skaff, H.; Dinsmore, A.D.; Emrick, T.; Russell, T.P. “Hierarchical Nanoparticle Assemblies Formed by Decorating Breath Figures” Nature Materials  2004, 3, 302-306. 

22. Sill, K.; Emrick, T. “Nitroxide-Mediated Radical Polymerization from CdSe Nanoparticles”, Chemistry of Materials  2004, 16, 1240-1243.  

21. Hong, R.; Fisher, N.O.; Verma, A.; Goodman, C.M.; Emrick, T.; Rotello, V.M. “Control of Protein Structure and Function through Surface Recognition by Tailored Nanoparticle Scaffolds” J. Am. Chem. Soc. 2004, 126, 739-743.   

20. Hong, R.; Emrick, T.; Rotello, V.M. “Monolayer-controlled Substrate Selectivity using Non-covalent Enzyme-Nanoparticle Conjugates”  J. Am. Chem. Soc. 2004, 126, 13572-13573.  


19. Breitenkamp, K.; Emrick, T.  “Novel Polymer Capsules from Amphiphilic Graft Copolymers and Ring-opening Cross Metathesis”  J. Am. Chem. Soc. 2003, 125, 12070-12071. 

18. Lin Y.; Skaff, H.; Boker, A.; Dinsmore, A.D.; Emrick, T.; Russell, T.P.  “Ultrathin Cross-linked Nanoparticle Membranes”  J. Am. Chem. Soc.  2003, 125, 12690-12691. 

17. Lin, Y.; Skaff, H.; Emrick, T.; Dinsmore, A.D.; Russell, T.P. “Nanoparticles at Liquid-Liquid Interfaces: Assembly, Displacement and Transport”  Science  2003, 299, 226-229.  

16. Misner, M.J.; Skaff, H.; Emrick, T.; Russell, T.P. "Directed Deposition of Nanoparticles using Diblock Copolymer Templates" Advanced Materials  2003, 15, 221-224. 

15. Skaff, H.; Emrick, T. "The Use of 4-Substituted Pyridines to Afford Amphiphilic, PEGylated Cadmium Selenide Nanoparticles" Chem. Comm. 2003, 52-53.

14. Ellzey, K.A.; Farris, R.J.; Emrick, T. “Synthetic and Thermal Studies of Bisphenol-C Containing Poly(aryletherketone)” Polym. Bull. 2003, 50, 235-242.  


13. Breitenkamp, K.; Simeone, J.; Jin, E.; Emrick, T. "Novel Amphiphilic Graft Copolymers Prepared by Ring-opening Metathesis Polymerization of Poly(ethylene glycol)-Substituted Cyclooctene Macromonomers”  Macromolecules  2002, 35, 9249-9252. 

12. Parrish, B.; Quansah, J.K.; Emrick, T. "Functional Polyesters Prepared by Polymerization of a-Allyl(d-valerolactone), and its Copolymerization with e-Caprolactone and d-Valerolactone" J. Polym. Sci. Part A: Polym. Chem.  2002, 40, 1983-1990.

11.  Skaff, H.; Ilker, M.F.; Coughlin, E.B.; Emrick, T.  “Preparation of Cadmium Selenide-Polyolefin Composites from Functional Phosphine Oxides and Ruthenium-based Metathesis” J. Am. Chem. Soc. 2002, 124, 5729-5733.


10.  Emrick, T.; Chang, H-T.; Fréchet, J.M.J.  "The Preparation of Hyperbranched Aromatic and Aliphatic Polyether Epoxies by Chloride-Catalyzed Proton Transfer Polymerization from AB(n) and A(2) + B-3 Monomers"  J. Polym. Sci. Part A: Polym. Chem. 2000, 33, 4850.

9.  Hecht, S.; Emrick, T.; Fréchet, J.M.J.  "Hyperbranched Porphyrins - A Rapid Synthetic Approach To Multiporphyrin Macromolecules"  Chem. Commun. 2000, 313.

8.  Emrick, T.; Chang, H.T.; Fréchet, J.M.J., Baccei, L., Woods, J.  "Hyperbranched Aromatic Epoxies in the Design of Adhesive Materials"  Polym. Bull. 2000, 45, 1. 


7.  Emrick, T.; Chang, H-T.; Fréchet, J.M.J  "An A(2)+B-3 Approach to Hyperbranched Aliphatic Polyethers Containing Chain End Epoxy Substituents"  Macromolecules 1999, 32, 6380.  

6.  Emrick, T.; Hayes, W.; Fréchet, J.M.J.  "A TEMPO Mediated “Living” Free Radical Approach to ABA Triblock Dendritic-Linear Hybrid Copolymers"  J. Polym. Sci. Part A: Polym. Chem. 1999, 37, 3748. 

5.  Emrick, T; Fréchet, J.M.J.  "Self-Assembly of Dendritic Structures"  Curr. Opin. Coll. In. Sci1999, 4, 15. 

4.  Eaton, P.E.; Pramod, K.; Emrick, T., Gilardi, R.  "Building with Cubane-1,4-diyl.  Synthesis of Aryl Substituted Cubanes, p-[n]Cubyls, and Cubane Separated Bis-Arenes"  J. Am. Chem. Soc. 1999, 121, 4111. 


3.  Yildirim, T.; Gehring, P.M.; Neumann D.A.; Eaton, P.E.; Emrick, T.  "Solid Cubane: A Brief Review" Carbon 1998, 36, 809.  

2. Hare, M.; Emrick, T.; Eaton, P.E.; Kass, S.R.  "Cubyl Anion Formation and an Experimental Determination of the Acidity and C-H Bond Dissociation Energy of Cubane"  J. Am. Chem. Soc. 1997, 119, 237.  

1.  Engling, G.; Emrick, T.; Hellmann, J.; McElroy, E.; Brandt, M.; Reingold, I.D.  "A Novel Approach to Bicyclo[3.3.0]octane-2,8-dione"  J. Org. Chem. 1994, 59, 1945-1946.